n-hexyl phenyl sulfoxide

Base Information

• Chemical Name: n-hexyl phenyl sulfoxide
• CAS No.: 117939-92-1
• Molecular Formula: C₁₂H₁₈OS
• Molecular Weight: 210.34
• Mol file: 117939-92-1.mol

Synonyms:

Chemical Property of n-hexyl phenyl sulfoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of n-hexyl phenyl sulfoxide

There total 10 articles about n-hexyl phenyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

hexyl phenyl sulfide (943-78-2) → n-hexyl phenyl sulfoxide (117939-92-1,131433-42-6,131433-44-8,13606-31-0)

Guidance literature:

With 1,2-diphenyl-1,1,2,2-tetrahydroperoxyethane; In tetrahydrofuran; at 20 ℃; for 0.2h; chemoselective reaction; Green chemistry;

DOI:10.1080/10426507.2016.1237951

Reference yield: 56.0%

(+/-)-7-(phenylsulfinyl)-2,3,8,8a-tetrahydroindolizin-5(1H)-one + n-hexylmagnesium bromide (3761-92-0) → n-hexyl phenyl sulfoxide (117939-92-1,131433-42-6,131433-44-8,13606-31-0) + 2,3,8,8a-tetrahydroindolizin-5(1H)-one (1127345-23-6) + C14H23NO (1380414-57-2)

Guidance literature:

(+/-)-7-(phenylsulfinyl)-2,3,8,8a-tetrahydroindolizin-5(1H)-one; n-hexylmagnesium bromide; In tetrahydrofuran; at 20 ℃; for 6h;

With acetic acid; In tetrahydrofuran; Cooling with ice;

With methanol; sodium tetrahydroborate; In tetrahydrofuran; for 0.5h;

DOI:10.1016/j.tet.2012.04.054

Reference yield:

hexyl phenyl sulfide (943-78-2) → phenyl hexyl sulfone (16823-63-5) + n-hexyl phenyl sulfoxide (117939-92-1,131433-42-6,131433-44-8,13606-31-0)

Guidance literature:

With dihydrogen peroxide; In methanol; at 20 ℃; for 10h; chemoselective reaction;

DOI:10.1016/j.tetlet.2009.03.106

upstream raw materials:

hexyl phenyl sulfide

n-butyllithium

Phenyl vinyl sulfoxide

trihexylaluminium

Downstream raw materials:

1-tert-butyldimethylsiloxyhexyl phenyl sulfide

hexyl phenyl sulfide

Refernces

• 1、 Ueno,Y. et al.. "-". . p. 2413 - 2416. Retrieved 1977.
• 2、 Khosravi, Kaveh,Naserifar, Shirin,Mahmoudi, Boshra,Khalaji, Kobra. "1,1,2,2-Tetrahydroperoxy-1,2-diphenylethane as new oxidant for chemoselective and catalyst free oxidation of sulfides to sulfoxides and sulfones". . p. 316 - 321. Retrieved 2017/02/18.