943-78-2Relevant articles and documents
Catalytic Reductive Cleavage of Poly(phenylene sulfide) Using a Hydrosilane
Minami, Yasunori,Matsuyama, Nao,Matsuo, Yasuaki,Tamura, Masanori,Sato, Kazuhiko,Nakajima, Yumiko
supporting information, p. 3351 - 3354 (2021/07/17)
The solvent-insoluble poly(phenylene sulfide) main chain was reductively cleaved by using triethylsilane as a hydrogen source under palladium/I c Hex catalytic conditions. After the reaction, benzene and bis(triethylsilyl) sulfide as a sulfide source were formed efficiently. This method could be operated on a gram scale.
Surfactant-Type Catalyst for Aerobic Oxidative Coupling of Hydrazine with Thiol in Water
Ren, Xuanhe,Tang, Shanyu,Li, Longjia,Li, Jiao,Liang, Helong,Li, Ganzhong,Yang, Guanyu,Li, Heng,Yuan, Bingxin
, p. 8683 - 8690 (2019/07/08)
A series of PEG-functionalized nitrogen ligands were developed to conduct an aerobic oxidative cross-coupling reaction between alkyl- or aryl-hydrazines with thiols in water. This surfactant-type catalyst enables high efficiencies and selectivities, while tolerating a large variety of functional groups. The mother liquor is still catalytically active after five runs.
Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization
Leicht, Hannes,G?ttker-Schnetmann, Inigo,Mecking, Stefan
supporting information, p. 6823 - 6826 (2017/05/31)
PhS- and PhNH-functionalized dienes are copolymerized efficiently with butadiene to stereoregular copolymers by [(mesitylene)Ni(allyl)][BArF4] (Ni-1). Overall polymerization rates and comonomer incorporations depend strongly on the l