(acetonitrile)pentacarbonylmanganese(I) cation

Base Information

• Chemical Name: (acetonitrile)pentacarbonylmanganese(I) cation
• CAS No.: 27674-37-9
• Molecular Formula: C₇H₃MnNO₅
• Molecular Weight: 236.043
• Mol file: 27674-37-9.mol

Synonyms:(acetonitrile)pentacarbonylmanganese(I) cation

Chemical Property of (acetonitrile)pentacarbonylmanganese(I) cation

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (acetonitrile)pentacarbonylmanganese(I) cation

There total 3 articles about (acetonitrile)pentacarbonylmanganese(I) cation which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimanganese decacarbonyl (10170-69-1) + acetonitrile (75-05-8,26809-02-9) → (acetonitrile)pentacarbonylmanganese(I) cation (27674-37-9) + pentacarbonylchloromanganese(I) (14100-30-2)

Guidance literature:

With copper dichloride; In acetonitrile; Schlenk flask, N2; the decacarbonyl is added to MeCN, oxidant (2 equiv)is added and stirred until dissolved; IR, UV; Kinetics;

DOI:10.1016/S0020-1693(00)96022-5

Reference yield:

dimanganese decacarbonyl (10170-69-1) + copper(II) bis(trifluoromethanesulfonate) (34946-82-2) + acetonitrile (75-05-8,26809-02-9) → (acetonitrile)pentacarbonylmanganese(I) cation (27674-37-9) + copper(I) triflate (34946-82-2,42152-44-3,109572-99-8)

Guidance literature:

In acetonitrile; Schlenk flask, N2; the decacarbonyl is added to MeCN, oxidant (2 equiv)is added and stirred until dissolved, soln. is heated (variation of temp.) for several h; IR, UV; Kinetics;

DOI:10.1016/S0020-1693(00)96022-5

Reference yield:

decacarbonylmanganeserhenium (14693-30-2) + copper(II) bis(trifluoromethanesulfonate) (34946-82-2) + acetonitrile (75-05-8,26809-02-9) → (acetonitrile)pentacarbonylmanganese(I) cation (27674-37-9) + Re(CO)5(CH3CN)(1+) (29421-17-8) + copper(I) triflate (34946-82-2,42152-44-3,109572-99-8)

Guidance literature:

In acetonitrile; Schlenk flask, N2; the decacarbonyl is added to MeCN, oxidant (2 equiv)is added and stirred until dissolved, soln. is heated (variation of temp.) for several h; IR, UV; Kinetics;

DOI:10.1016/S0020-1693(00)96022-5

upstream raw materials:

dimanganese decacarbonyl

copper(II) bis(trifluoromethanesulfonate)

acetonitrile

decacarbonylmanganeserhenium

Downstream raw materials:

dimanganese decacarbonyl

Mn₂(CO)8(triphenyl phosphite)2

Mn₂(CO)9(triphenyl phosphite)

Mn₂(CO)8(dimethylphenylphosphine)2