[(pentamethylcyclopentadienyl)RuH₂(P(i-Pr)2Ph)2][B(3,5-(CF₃)2C₆H₃)4]

Base Information

Chemical Name:[(pentamethylcyclopentadienyl)RuH₂(P(i-Pr)2Ph)2][B(3,5-(CF₃)2C₆H₃)4]
CAS No.:478552-32-8
Molecular Formula:C₃₂H₁₂BF₂₄*C₃₄H₅₅P₂Ru
Molecular Weight:1490.05
Hs Code.:

[(pentamethylcyclopentadienyl)RuH<sub>2</sub>(P(i-Pr)2Ph)2][B(3,5-(CF<sub>3</sub>)2C<sub>6</sub>H<sub>3</sub>)4]

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Chemical Property of [(pentamethylcyclopentadienyl)RuH₂(P(i-Pr)2Ph)2][B(3,5-(CF₃)2C₆H₃)4]

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Technology Process of [(pentamethylcyclopentadienyl)RuH₂(P(i-Pr)2Ph)2][B(3,5-(CF₃)2C₆H₃)4]

There total 1 articles about [(pentamethylcyclopentadienyl)RuH₂(P(i-Pr)2Ph)2][B(3,5-(CF₃)2C₆H₃)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: [(η(5)-pentamethylcyclopentadienyl)RuCl]4

: 1333-74-0
hydrogen

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 6372-43-6
diisopropylphenylphosphane

: 478552-32-8
[(pentamethylcyclopentadienyl)RuH₂(P(i-Pr)2Ph)2][B(3,5-(CF₃)2C₆H₃)4]

Guidance literature:: In fluorobenzene; byproducts: NaCl; under dry Ar, Schlenk technique; to the soln. of Ru complex was added PPh(i-Pr)2, to this soln. under H2 atm. was added NaBAr4, mixt. was stirred at room temp. for 30 min; mixt. was filtered, filtrate was evapd. to dryness, ppt. was washed withpetroleum ether, dried in vac.; elem. anal.;
DOI:10.1021/om020359r

Reference yield:

: 478552-32-8
[(pentamethylcyclopentadienyl)RuH₂(P(i-Pr)2Ph)2][B(3,5-(CF₃)2C₆H₃)4]

: 478552-33-9
[(pentamethylcyclopentadienyl)RuH(P(i-Pr)2Ph)2]

Guidance literature:: With KO(t-Bu); In tetrahydrofuran; under dry Ar, Schlenk technique; the soln. of Ru complex was treated with solid KO(t-Bu), mixt. was stirred at room temp. for 1 h; solvent was removed, residue was extd. with petroleum ether, extract wasfiltered, concd. and cooled to -20°C, yield:60-70%; elem. anal.;
DOI:10.1021/om020359r