bis(dimethylamino)(phenylimido)dichlorotitanium

Base Information

• Chemical Name: bis(dimethylamino)(phenylimido)dichlorotitanium
• CAS No.: 402937-77-3
• Molecular Formula: C₁₀H₁₉Cl₂N₃Ti
• Molecular Weight: 300.067
• Mol file: 402937-77-3.mol

Synonyms:

Chemical Property of bis(dimethylamino)(phenylimido)dichlorotitanium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(dimethylamino)(phenylimido)dichlorotitanium

There total 4 articles about bis(dimethylamino)(phenylimido)dichlorotitanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

tetrakis(dimethylamido)titanium(IV) + chloro-trimethyl-silane (75-77-4) + aniline (62-53-3) → bis(dimethylamino)(phenylimido)dichlorotitanium (402937-77-3)

Guidance literature:

In toluene; under Ar, Schlenk techniques; amine added to soln. of Ti compd. in toluene at room temp. (molar ratio = 1:1), about 8 equiv. of Me3SiCl added atroom temp., mixt. stirred at room temp. overnight; crystd. (without or on addn. of pentane) or evapn. of soln., solid washed with pentane, dried under vac., recrystd. from toluene/pentane; elem. anal.;

DOI:10.1002/ejic.200600475

Reference yield:

diphenyl hydrazine (122-66-7) → (HNMe2)2Cl2Ti(NPh) (402937-77-3)

Guidance literature:

Multi-step reaction with 2 steps

1: benzene

2: α,α,α-trifluorotoluene / Heating

With α,α,α-trifluorotoluene; In benzene;

DOI:10.1038/nchem.2386

Reference yield:

tetrakis(dimethylamido)titanium(IV) + chloro-trimethyl-silane (75-77-4) + aniline (62-53-3) → (HNMe2)2Cl2Ti(NPh) (402937-77-3)

Guidance literature:

In toluene; 1 equiv of Ti(NMe2)4, 1 equiv of C6H5NH2, 8 equiv of Me3SiCl in toluene,80°C;

DOI:10.1021/om0342762

upstream raw materials:

chloro-trimethyl-silane

aniline

diphenyl hydrazine

Downstream raw materials:

[Ti(NPh)(1,4,7-trimethyl triazacyclononane)Cl₂]

Ti(pyridine-2,6-bis(4,6-di-tert-butylphenolate))(HNMe₂)(NPh)