ethyl 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoate

Base Information

• Chemical Name: ethyl 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoate
• CAS No.: 1299490-78-0
• Molecular Formula: C₁₈H₁₈N₂O₃
• Molecular Weight: 310.353
• Mol file: 1299490-78-0.mol

Synonyms:

Chemical Property of ethyl 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethyl 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoate

There total 3 articles about ethyl 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

allyl bromide (106-95-6) + ethyl 4-[(4-hydroxyphenyl)diazenyl]benzoate (4418-89-7) → ethyl 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoate (1299490-78-0)

Guidance literature:

With potassium carbonate; potassium iodide; In acetone; for 24h; Reflux; Inert atmosphere;

DOI:10.1039/c3nj00359k

Reference yield:

p-aminoethylbenzoate (94-09-7) → ethyl 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoate (1299490-78-0)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrogenchloride; sodium nitrite

2: potassium carbonate; potassium iodide / acetone / 24 h / Reflux; Inert atmosphere

With hydrogenchloride; potassium carbonate; potassium iodide; sodium nitrite; In acetone;

DOI:10.1039/c3nj00359k

Reference yield:

phenol (108-95-2,27073-41-2) → ethyl 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoate (1299490-78-0)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrogenchloride; sodium nitrite

2: potassium carbonate; potassium iodide / acetone / 24 h / Reflux; Inert atmosphere

With hydrogenchloride; potassium carbonate; potassium iodide; sodium nitrite; In acetone;

DOI:10.1039/c3nj00359k

upstream raw materials:

p-aminoethylbenzoate

allyl bromide

ethyl 4-[(4-hydroxyphenyl)diazenyl]benzoate

phenol

Downstream raw materials:

4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoic acid