4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoic acid

Base Information

• Chemical Name: 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoic acid
• CAS No.: 1299490-81-5
• Molecular Formula: C₁₆H₁₄N₂O₃
• Molecular Weight: 282.299
• Mol file: 1299490-81-5.mol

Synonyms:

Chemical Property of 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoic acid

There total 4 articles about 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

ethyl 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoate (1299490-78-0) → 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoic acid (1299490-81-5)

Guidance literature:

With water; potassium hydroxide; In methanol; for 4h; Reflux;

DOI:10.1039/c3nj00359k

Reference yield:

p-aminoethylbenzoate (94-09-7) → 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoic acid (1299490-81-5)

Guidance literature:

Multi-step reaction with 3 steps

1: hydrogenchloride; sodium nitrite

2: potassium carbonate; potassium iodide / acetone / 24 h / Reflux; Inert atmosphere

3: potassium hydroxide; water / methanol / 4 h / Reflux

With hydrogenchloride; water; potassium carbonate; potassium iodide; potassium hydroxide; sodium nitrite; In methanol; acetone;

DOI:10.1039/c3nj00359k

Reference yield:

ethyl 4-[(4-hydroxyphenyl)diazenyl]benzoate (4418-89-7) → 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoic acid (1299490-81-5)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium carbonate; potassium iodide / acetone / 24 h / Reflux; Inert atmosphere

2: potassium hydroxide; water / methanol / 4 h / Reflux

With water; potassium carbonate; potassium iodide; potassium hydroxide; In methanol; acetone;

DOI:10.1039/c3nj00359k

upstream raw materials:

p-aminoethylbenzoate

ethyl 4-[(4-hydroxyphenyl)diazenyl]benzoate

phenol

ethyl 4-{2-[4-(prop-2-enyloxy)phenyl]diazenyl}benzoate