meso-tetraphenylporphyrinato(η1-nitrito)(nitrosyl)iron

Base Information

• Chemical Name: meso-tetraphenylporphyrinato(η1-nitrito)(nitrosyl)iron
• CAS No.: 89935-21-7
• Molecular Formula: C₄₄H₂₈FeN₆O₃
• Molecular Weight: 744.592
• Mol file: 89935-21-7.mol

Synonyms:

Chemical Property of meso-tetraphenylporphyrinato(η1-nitrito)(nitrosyl)iron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of meso-tetraphenylporphyrinato(η1-nitrito)(nitrosyl)iron

There total 5 articles about meso-tetraphenylporphyrinato(η1-nitrito)(nitrosyl)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

μ-oxo-bis[α,β,γ,δ-tetraphenylporphinatoiron] (12582-61-5) + nitrogen(II) oxide (10102-43-9) + Nitrogen dioxide (10102-44-0) → meso-tetraphenylporphyrinato(η1-nitrito)(nitrosyl)iron (880172-71-4,89935-21-7,935699-71-1)

Guidance literature:

In chloroform; Fe complex dissolved in CHCl3 in Schlenk flask under Ar, soln. stirred for a few min, excess of NO2 introduced, air injected into flask, soln. stirred under NO/O2 atm. for 1 h; hexane added, ppt. filtered off and stored under Ar in a freezer;

DOI:10.1021/ja801860u

Reference yield:

(nitrosyl)(meso-tetraphenylporphyrinato)iron(II) (52674-29-0) + nitrogen(II) oxide (10102-43-9) → meso-tetraphenylporphyrinato(η1-nitrito)(nitrosyl)iron (880172-71-4,89935-21-7,935699-71-1) + meso-tetraphenylporphyrinato(η1-nitrito)iron(III) (935699-70-0) + dinitrogen monoxide (10024-97-2)

Guidance literature:

In not given; byproducts: NO2; No-Fe(TPP) in toluene or chloroform was placed in quartz cuvette; the cell was evacuated; then NO was introduced; monitoring the UV-vis spectra; Kinetics;

DOI:10.1021/ja993643r

Reference yield:

[Fe(tetraphenylporphinate)(NO2)(NO)] → meso-tetraphenylporphyrinato(η1-nitrito)(nitrosyl)iron (880172-71-4,89935-21-7,935699-71-1)

Guidance literature:

In potassium bromide; Irradiation (UV/VIS); Fe-complex was irradiated in KBr pellet at 200 K for 10 min; detected by IR spectroscopy;

DOI:10.1021/ja0488986

upstream raw materials:

(nitrosyl)(meso-tetraphenylporphyrinato)iron(II)

nitrogen(II) oxide

oxygen

μ-oxo-bis[α,β,γ,δ-tetraphenylporphinatoiron]