(D,L)-O-ferrocenylmethyl-N-(carboxybenzyloxy)tyrosine methyl ester

Base Information

Chemical Name:(D,L)-O-ferrocenylmethyl-N-(carboxybenzyloxy)tyrosine methyl ester
CAS No.:828923-54-2
Molecular Formula:C₂₉H₂₉FeNO₅
Molecular Weight:527.4
Hs Code.:

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Chemical Property of (D,L)-O-ferrocenylmethyl-N-(carboxybenzyloxy)tyrosine methyl ester

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Technology Process of (D,L)-O-ferrocenylmethyl-N-(carboxybenzyloxy)tyrosine methyl ester

There total 1 articles about (D,L)-O-ferrocenylmethyl-N-(carboxybenzyloxy)tyrosine methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1273-86-5
1-ferrocenylmethanol

: 21467-33-4
N-benzyloxycarbonyl-D,L-tyrosine methyl ester

: 828923-54-2,828923-74-6,828923-76-8
(D,L)-O-ferrocenylmethyl-N-(carboxybenzyloxy)tyrosine methyl ester

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; under N2; tyrosine methyl ester and PPh3 added at room temp. to soln. ofFe complex in dry THF; cooled to -30°C; THF soln. of DEAD added slowly; stirred at room temp. for 18 h; solvent evapd.; dissolved in CH2Cl2; washed with brine; aq. phase extd. (CH2Cl2); combined org. phase dried (Na2SO4); evapd.; purified by columnchromy. (silica gel, light petroleum-AcOEt 7:3); elem. anal.;
DOI:10.1016/j.jorganchem.2004.09.049

Reference yield: 75.0%

: 828923-54-2,828923-74-6,828923-76-8
(D,L)-O-ferrocenylmethyl-N-(carboxybenzyloxy)tyrosine methyl ester

: 540-69-2
ammonium formate

: 828923-80-4,828923-78-0,828923-55-3
(D,L)-O-ferrocenylmethyl-tyrosine methyl ester

Guidance literature:: With catalyst: Pd-C; In methanol; dichloromethane; under N2; Pd-C and HCO2NH4 added at room temp. to soln. of Fe complex inCH2Cl2-MeOH; stirred at room temp. overnight; filtered over Celite; solvent evapd.; dissolved in AcOEt; washed (brine); aq. phase extd. (AcOEt); combined org. phase washed (H2O); dried (Na2SO4); evapd.; purified by column chromy. (silica gel, AcOEt); elem. anal.;
DOI:10.1016/j.jorganchem.2004.09.049