Ethyl 2-(4-(methylthio)phenyl)-2-oxoacetate

Base Information

Chemical Name:Ethyl 2-(4-(methylthio)phenyl)-2-oxoacetate
CAS No.:62936-31-6
Molecular Formula:C11H12O3S
Molecular Weight:224.28
Hs Code.:2930909090
European Community (EC) Number:675-589-6
DSSTox Substance ID:DTXSID90978764
Nikkaji Number:J2.275.937J
Wikidata:Q72476258
Mol file:62936-31-6.mol

Synonyms:62936-31-6;Ethyl 2-(4-(methylthio)phenyl)-2-oxoacetate;Ethyl 4-thiomethylbenzoylformate;ethyl 2-(4-methylsulfanylphenyl)-2-oxoacetate;Ethyl 4-(methylthio)benzoylformate;SCHEMBL640427;DTXSID90978764;AAVSFTKDXIEMEI-UHFFFAOYSA-N;MFCD01319625;AKOS016017107;CS-0364545;Ethyl2-(4-(methylthio)phenyl)-2-oxoacetate;FT-0713260;Ethyl [4-(methylsulfanyl)phenyl](oxo)acetate;(4-methylsulfanylphenyl)oxoacetic acid ethyl ester;(4-methylsulfanyl-phenyl)-oxo-acetic acid ethyl ester;alpha-Oxo-4-(methylthio)benzeneacetic acid ethyl ester

Suppliers and Price of Ethyl 2-(4-(methylthio)phenyl)-2-oxoacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Rieke Metals
(4-Methylsulfanylphenyl)oxoaceticacidethylester
1g
$ 488.00

Rieke Metals
(4-Methylsulfanylphenyl)oxoaceticacidethylester
5g
$ 1106.00

Matrix Scientific
Ethyl 4-thiomethylbenzoylformate
5g
$ 1165.00

Matrix Scientific
Ethyl 4-thiomethylbenzoylformate
2g
$ 538.00

Matrix Scientific
Ethyl 4-thiomethylbenzoylformate
1g
$ 345.00

Crysdot
Ethyl2-(4-(methylthio)phenyl)-2-oxoacetate 95+%
10g
$ 466.00

American Custom Chemicals Corporation
ETHYL 4-THIOMETHYLBENZOYLFORMATE 95.00%
1G
$ 958.07

Alichem
Ethyl2-(4-(methylthio)phenyl)-2-oxoacetate
5g
$ 400.00

Total 36 raw suppliers

Chemical Property of Ethyl 2-(4-(methylthio)phenyl)-2-oxoacetate

Chemical Property:

Vapor Pressure:7.48E-05mmHg at 25°C
Refractive Index:1.555
Boiling Point:342.5 °C at 760 mmHg
Flash Point:163.4 °C
PSA：68.67000
Density:1.2 g/cm³
LogP:2.15430
XLogP3:2.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:224.05071541
Heavy Atom Count:15
Complexity:232

Purity/Quality:

98%Min ^*data from raw suppliers

(4-Methylsulfanylphenyl)oxoaceticacidethylester ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C(=O)C1=CC=C(C=C1)SC

Technology Process of Ethyl 2-(4-(methylthio)phenyl)-2-oxoacetate

There total 5 articles about Ethyl 2-(4-(methylthio)phenyl)-2-oxoacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 100-68-5
methyl-phenyl-thioether

: 4755-77-5
Ethyl oxalyl chloride

: 62936-31-6
(4-methylsulfanylphenyl)oxoacetic acid ethyl ester

Guidance literature:: Ethyl oxalyl chloride; aluminum (III) chloride; In dichloromethane;

methyl-phenyl-thioether; In dichloromethane; at 10 - 25 ℃; for 2h;

Reference yield: 74.0%

: 18620-04-7
4-thioanisolemagnesium bromide

: 95-92-1
oxalic acid diethyl ester

: 62936-31-6
(4-methylsulfanylphenyl)oxoacetic acid ethyl ester

Guidance literature:: In diethyl ether; at -78 - 10 ℃;
DOI:10.1021/jo00231a036

Reference yield:

: 100-68-5
methyl-phenyl-thioether

: 62936-31-6
(4-methylsulfanylphenyl)oxoacetic acid ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: AlCl₃ / CS₂

2: H₂SO₄ / benzene

With aluminium trichloride; sulfuric acid; In carbon disulfide; benzene;