Ethanethioic acid, S-(4'-iodo[1,1'-biphenyl]-4-yl) ester

Base Information

Chemical Name:Ethanethioic acid, S-(4'-iodo[1,1'-biphenyl]-4-yl) ester
CAS No.:933779-24-9
Molecular Formula:C₁₄H₁₁IOS
Molecular Weight:354.211
Hs Code.:
Mol file:933779-24-9.mol

Synonyms:Ethanethioic acid, S-(4'-iodo[1,1'-biphenyl]-4-yl) ester

Suppliers and Price of Ethanethioic acid, S-(4'-iodo[1,1'-biphenyl]-4-yl) ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Ethanethioic acid, S-(4'-iodo[1,1'-biphenyl]-4-yl) ester

Chemical Property:

PSA：42.37000
LogP:4.59680

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

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Technology Process of Ethanethioic acid, S-(4'-iodo[1,1'-biphenyl]-4-yl) ester

There total 1 articles about Ethanethioic acid, S-(4'-iodo[1,1'-biphenyl]-4-yl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 3001-15-8
4,4'-diiodobiphenyl

: 75-36-5
acetyl chloride

: 933779-24-9
4-iodo-4'-thioacetylbiphenyl

Guidance literature:: 4,4'-diiodobiphenyl; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; for 0.166667h;

With sulfur; In tetrahydrofuran; at 0 ℃; for 0.75h;

acetyl chloride; In tetrahydrofuran; at 25 ℃;
DOI:10.1016/j.jorganchem.2008.09.031

Reference yield: 85.0%

: 933779-24-9
4-iodo-4'-thioacetylbiphenyl

: 14221-01-3
tetrakis(triphenylphosphine) palladium⁽⁰⁾

: 934273-47-9
trans-[(CH₃C(O)S-4-C₆H₄C₆H₄)Pd(PPh₃)2I]

Guidance literature:: In toluene; byproducts: PPh3; (N2); Pd complex (1 equiv.) was added to soln. of iodide in toluene at 25°C; stirred for 2 h; volatiles evapd. (vac.); dissolved in CH2Cl2; hexane added; decanted; residue washed (hexane); elem. anal.;
DOI:10.1016/j.jorganchem.2008.09.031

Reference yield:

: 933779-24-9
4-iodo-4'-thioacetylbiphenyl

: 1271-47-2
ferroceneacetylene

: 918403-40-4
acetyl protected ferrocene-substituted biphenyl ethynyl thiol

Guidance literature:: With (Ph₃P)2PdCl₂; CuI; In triethylamine; (N2); std. Schlenk technique; catalytic amt. of Pd complex/CuI was addedto Fe complex and I(C6H4)2SC(O)Me in Et3N at 25°C; stirred at 50 °C for 24 h; volatiles removed (vac.); chromd. (silica gel, hexane/CH2Cl2, 3/2); evapd. (vac.); elem. anal.;
DOI:10.1016/j.jorganchem.2006.12.002