S(CH₂-2-C₆H₄BiPh₂)2

Base Information

Chemical Name:S(CH₂-2-C₆H₄BiPh₂)2
CAS No.:1266397-39-0
Molecular Formula:C₃₈H₃₂Bi₂S
Molecular Weight:938.699
Hs Code.:

S(CH<sub>2</sub>-2-C<sub>6</sub>H<sub>4</sub>BiPh<sub>2</sub>)2

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Chemical Property of S(CH₂-2-C₆H₄BiPh₂)2

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Technology Process of S(CH₂-2-C₆H₄BiPh₂)2

There total 2 articles about S(CH₂-2-C₆H₄BiPh₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: 39248-62-9
diphenylbismuthanyl bromide

: 84035-84-7
bis(2-bromobenzyl) sulfide

: 1266397-39-0
S(CH₂-2-C₆H₄BiPh₂)2

Guidance literature:: With n-BuLi; In diethyl ether; hexane; (N2); std. Schlenk technique; soln. of BuLi in hexane was added dropwiseto soln. of S(CH2C6H4Br)2 in Et2O at -30°C; stirred for 3 h at - 30°C; Bi compd. was added; stirred overnight; warmed to room temp.; evapd. (vac.); extd. (toluene); filtered; distd. H2O added; org. layer septd.; dried (MgSO4); evapd. (vac.); washed (acetone); crystd. (satd. toluene); elem. anal.;
DOI:10.1021/om1010148

Reference yield:

: 603-33-8
triphenylbismuthane

: 1266397-39-0
S(CH₂-2-C₆H₄BiPh₂)2

Guidance literature:: Multi-step reaction with 2 steps

1: diethyl ether

2: n-BuLi / diethyl ether; hexane

With n-BuLi; In diethyl ether; hexane;
DOI:10.1021/om1010148

Reference yield: 16.0%

: 14104-20-2
silver tetrafluoroborate

: 12078-28-3,38979-86-1
dicarbonylcyclopentadienyliodoiron(II)

: 1266397-39-0
S(CH₂-2-C₆H₄BiPh₂)2

: [((C₅H₅)Fe(CO)2)2(S(CH₂-2-C₆H₄BiPh₂)2)][BF₄]2

Guidance literature:: In tetrahydrofuran; dichloromethane; (N2); std. Schlenk technique; Fe complex was dissolved in CH2Cl2/THF (1 drop); added to soln. of Ag salt in CH2Cl2; stirred for 2 h in dark; filtered; cooled to -78°C; soln. of Bi compd. in CH2Cl2 was added; stirred for 16 h at room temp.; concd. (vac.); hexane added; filtered; dried (vac.);
DOI:10.1021/om1010148