1,1-bis[4-(3-dimethylaminopropoxy)phenyl]-2-ferrocenyl-but-1-ene

Base Information

Chemical Name:1,1-bis[4-(3-dimethylaminopropoxy)phenyl]-2-ferrocenyl-but-1-ene
CAS No.:1291080-35-7
Molecular Formula:C₃₆H₄₆FeN₂O₂
Molecular Weight:594.62
Hs Code.:

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Chemical Property of 1,1-bis[4-(3-dimethylaminopropoxy)phenyl]-2-ferrocenyl-but-1-ene

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Technology Process of 1,1-bis[4-(3-dimethylaminopropoxy)phenyl]-2-ferrocenyl-but-1-ene

There total 1 articles about 1,1-bis[4-(3-dimethylaminopropoxy)phenyl]-2-ferrocenyl-but-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 177840-82-3
1,1’-bis-(4-hydroxyphenyl)-2-ferrocenylbut-1-ene

: 124-40-3
dimethyl amine

: 109-64-8
1,3-dibromo-propane

: 1291080-35-7
1,1-bis[4-(3-dimethylaminopropoxy)phenyl]-2-ferrocenyl-but-1-ene

Guidance literature:: With sodium ethanolate; H₂O; In ethanol; Ar; Fc compd. added to soln. of NaOEt, reflux (1h), Br(CH2)3Br added, reflux (1h), then hydrolized at room temp., extd. (CH2Cl2), column chromy.(petroleum ether), resulting dibromo compd. added to 2M soln. of HNMe2 in MeOH, 60°C, 24 h, cooled; soln. concd., dissolved in CH2Cl2, washed (NaHCO3, H2O), dried (MgSO4), concd., chromy. (SiO2, acetone, then 10% Et3N in acetone);
DOI:10.1016/j.jorganchem.2010.09.015

Reference yield: 84.0%

: 1291080-35-7
1,1-bis[4-(3-dimethylaminopropoxy)phenyl]-2-ferrocenyl-but-1-ene

: 77-92-9,906507-37-7
citric acid

: 1291080-44-8
1,1-bis-[4-(3-dimethylammoniumpropoxy)phenyl]-2-ferrocenyl-but-1-ene citrate

Guidance literature:: In tetrahydrofuran; diethyl ether; under Ar, Schlenk techniques; Fc compd. dissolved in THF, then Et2O added, then soln. of citric aicd in THF added dropwise, stirring (20 min); solid washed (Et2O), dried (vac.); traces of Et2O and THF;
DOI:10.1016/j.jorganchem.2010.09.015