Technology Process of 4-{9-[4-bromo-2-(1H,1H,2H,2H,3H,3H-perfluorononyl)phenoxy]nonyl}-2,2-dimethyl-1,3-dioxolane
There total 6 articles about 4-{9-[4-bromo-2-(1H,1H,2H,2H,3H,3H-perfluorononyl)phenoxy]nonyl}-2,2-dimethyl-1,3-dioxolane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
pyridinium p-toluenesulfonate;
at 25 ℃;
for 24h;
DOI:10.1021/ja200822z
- Guidance literature:
-
Multi-step reaction with 4 steps
1: lithium aluminium tetrahydride / diethyl ether / Reflux
2: hydrogen bromide; dimethyl sulfoxide / acetic acid / -5 - 10 °C
3: potassium carbonate / acetonitrile / 2 h / Reflux; Inert atmosphere
4: pyridinium p-toluenesulfonate / 24 h / 25 °C
With
lithium aluminium tetrahydride; hydrogen bromide; pyridinium p-toluenesulfonate; potassium carbonate; dimethyl sulfoxide;
In
diethyl ether; acetic acid; acetonitrile;
DOI:10.1021/ja200822z
- Guidance literature:
-
Multi-step reaction with 5 steps
1: tetrakis(triphenylphosphine) palladium(0) / hexane / 36 h / 0 - 25 °C / Inert atmosphere
2: lithium aluminium tetrahydride / diethyl ether / Reflux
3: hydrogen bromide; dimethyl sulfoxide / acetic acid / -5 - 10 °C
4: potassium carbonate / acetonitrile / 2 h / Reflux; Inert atmosphere
5: pyridinium p-toluenesulfonate / 24 h / 25 °C
With
lithium aluminium tetrahydride; tetrakis(triphenylphosphine) palladium(0); hydrogen bromide; pyridinium p-toluenesulfonate; potassium carbonate; dimethyl sulfoxide;
In
diethyl ether; hexane; acetic acid; acetonitrile;
DOI:10.1021/ja200822z
