2,2-dimethyl-4-(9-{4'-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-3-(1H,1H,2H,2H,3H,3H-perfluorononyl)biphenyl-4-yloxy}nonyl)-1,3-dioxolane

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Chemical Name:2,2-dimethyl-4-(9-{4'-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-3-(1H,1H,2H,2H,3H,3H-perfluorononyl)biphenyl-4-yloxy}nonyl)-1,3-dioxolane
CAS No.:1306771-55-0
Molecular Formula:C₄₁H₅₁F₁₃O₆
Molecular Weight:886.832
Hs Code.:

Synonyms:

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Chemical Property of 2,2-dimethyl-4-(9-{4'-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-3-(1H,1H,2H,2H,3H,3H-perfluorononyl)biphenyl-4-yloxy}nonyl)-1,3-dioxolane

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Technology Process of 2,2-dimethyl-4-(9-{4'-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-3-(1H,1H,2H,2H,3H,3H-perfluorononyl)biphenyl-4-yloxy}nonyl)-1,3-dioxolane

There total 7 articles about 2,2-dimethyl-4-(9-{4'-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-3-(1H,1H,2H,2H,3H,3H-perfluorononyl)biphenyl-4-yloxy}nonyl)-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 1306771-50-5
4-{9-[4-bromo-2-(1H,1H,2H,2H,3H,3H-perfluorononyl)phenoxy]nonyl}-2,2-dimethyl-1,3-dioxolane

: 351432-33-2
4-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]benzene boronic acid

: 1306771-55-0
2,2-dimethyl-4-(9-{4'-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-3-(1H,1H,2H,2H,3H,3H-perfluorononyl)biphenyl-4-yloxy}nonyl)-1,3-dioxolane

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydrogencarbonate; In 1,2-dimethoxyethane; water; for 6h; Reflux; Inert atmosphere;
DOI:10.1021/ja200822z

Reference yield:

: C₁₅H₁₀F₁₃IO

: 1306771-55-0
2,2-dimethyl-4-(9-{4'-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-3-(1H,1H,2H,2H,3H,3H-perfluorononyl)biphenyl-4-yloxy}nonyl)-1,3-dioxolane

Guidance literature:: Multi-step reaction with 5 steps

1: lithium aluminium tetrahydride / diethyl ether / Reflux

2: hydrogen bromide; dimethyl sulfoxide / acetic acid / -5 - 10 °C

3: potassium carbonate / acetonitrile / 2 h / Reflux; Inert atmosphere

4: pyridinium p-toluenesulfonate / 24 h / 25 °C

5: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydrogencarbonate / 1,2-dimethoxyethane; water / 6 h / Reflux; Inert atmosphere

With lithium aluminium tetrahydride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; hydrogen bromide; pyridinium p-toluenesulfonate; sodium hydrogencarbonate; potassium carbonate; dimethyl sulfoxide; In 1,2-dimethoxyethane; diethyl ether; water; acetic acid; acetonitrile; 5: Suzuki coupling;
DOI:10.1021/ja200822z

Reference yield:

: 355-43-1
n-perfluorohexyl iodide

: 1306771-55-0
2,2-dimethyl-4-(9-{4'-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-3-(1H,1H,2H,2H,3H,3H-perfluorononyl)biphenyl-4-yloxy}nonyl)-1,3-dioxolane

Guidance literature:: Multi-step reaction with 6 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / hexane / 36 h / 0 - 25 °C / Inert atmosphere

2: lithium aluminium tetrahydride / diethyl ether / Reflux

3: hydrogen bromide; dimethyl sulfoxide / acetic acid / -5 - 10 °C

4: potassium carbonate / acetonitrile / 2 h / Reflux; Inert atmosphere

5: pyridinium p-toluenesulfonate / 24 h / 25 °C

6: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydrogencarbonate / 1,2-dimethoxyethane; water / 6 h / Reflux; Inert atmosphere

With lithium aluminium tetrahydride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; hydrogen bromide; pyridinium p-toluenesulfonate; sodium hydrogencarbonate; potassium carbonate; dimethyl sulfoxide; In 1,2-dimethoxyethane; diethyl ether; hexane; water; acetic acid; acetonitrile; 6: Suzuki coupling;
DOI:10.1021/ja200822z