3,5,8-Trioxabicyclo[5.1.0]octane, 4,4-dimethyl-, cis-

Base Information

Chemical Name:3,5,8-Trioxabicyclo[5.1.0]octane, 4,4-dimethyl-, cis-
CAS No.:100572-41-6
Molecular Formula:C7H12O3
Molecular Weight:144.17
Hs Code.:
European Community (EC) Number:600-110-4
UNII:UH2578TWH3
DSSTox Substance ID:DTXSID601195327
Nikkaji Number:J823.776J
Mol file:100572-41-6.mol

Synonyms:100572-41-6;UH2578TWH3;UNII-UH2578TWH3;3,5,8-Trioxabicyclo[5.1.0]octane, 4,4-dimethyl-, cis-;3,5,8-Trioxabicyclo(5.1.0)octane, 4,4-dimethyl-;4,4-Dimethyl-3,5,8-trioxabicyclo(5.1.0)octane, cis-;3,5,8-Trioxabicyclo(5.1.0)octane, 4,4-dimethyl-, cis-;3,5,8-Trioxabicyclo(5.1.0)octane, 4,4-dimethyl-, (1R,7S)-rel-;3,5,8-Trioxabicyclo[5.1.0]octane, 4,4-dimethyl-;4,4-dimethyl-3,5,8-Trioxabicyclo[5.1.0]octane, cis-;3,5,8-Trioxabicyclo[5.1.0]octane, 4,4-dimethyl-, (1R,7S)-rel-;DTXSID601195327;(1R,7S)-4,4-Dimethyl-3,5,8-trioxabicyclo[5.1.0]octane;rel-(1R,7S)-4,4-Dimethyl-3,5,8-trioxabicyclo[5.1.0]octane

Suppliers and Price of 3,5,8-Trioxabicyclo[5.1.0]octane, 4,4-dimethyl-, cis-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 3,5,8-Trioxabicyclo[5.1.0]octane, 4,4-dimethyl-, cis-

Chemical Property:

Vapor Pressure:1.3mmHg at 25°C
XLogP3:0.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:0
Exact Mass:144.078644241
Heavy Atom Count:10
Complexity:130

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(OCC2C(O2)CO1)C
Isomeric SMILES:CC1(OC[C@@H]2[C@@H](O2)CO1)C

Technology Process of 3,5,8-Trioxabicyclo[5.1.0]octane, 4,4-dimethyl-, cis-

There total 2 articles about 3,5,8-Trioxabicyclo[5.1.0]octane, 4,4-dimethyl-, cis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 1003-83-4
2,2-dimethyl-4,7-dihydro-1,3-dioxepin

: 100572-41-6
4,4-dimethyl-3,5,8-trioxa-bicyclo-[5.1.0]octane

Guidance literature:: With disodium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1016/0957-4166(95)00158-L

Reference yield:

: 77-76-9
2,2-dimethoxy-propane

: 100572-41-6
4,4-dimethyl-3,5,8-trioxa-bicyclo-[5.1.0]octane

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / p-toluenesulfonic acid / 0.25 h

2: 68 percent / 50-60percent m-CPBA, Na₂HPO₄ / CH₂Cl₂

With disodium hydrogenphosphate; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1016/0957-4166(95)00158-L

Reference yield: 99.5%

: 3886-69-9
(R)-1-phenyl-ethyl-amine

: 100572-41-6
4,4-dimethyl-3,5,8-trioxa-bicyclo-[5.1.0]octane

: (5S,6R)-2,2-dimethyl-6-<(R)-1-phenylmethylamino>-1,3-dioxepan-5-ol

Guidance literature:: With titanium(IV) isopropylate; water; (S)-[1,1']-binaphthalenyl-2,2'-diol; In n-heptane; toluene; at 40 ℃; for 24h;
DOI:10.1021/jo9900883