hexamethylbenzene-dihydrido-triphenylphosphine-ruthenium(II)

Base Information

• Chemical Name: hexamethylbenzene-dihydrido-triphenylphosphine-ruthenium(II)
• CAS No.: 82498-42-8
• Molecular Formula: C₃₀H₃₅PRu
• Molecular Weight: 527.652
• Mol file: 82498-42-8.mol

Synonyms:

Chemical Property of hexamethylbenzene-dihydrido-triphenylphosphine-ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hexamethylbenzene-dihydrido-triphenylphosphine-ruthenium(II)

There total 3 articles about hexamethylbenzene-dihydrido-triphenylphosphine-ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

(η6-C6Me6)Ru(OCOCF3)2(PPh3) (82498-35-9) → hexamethylbenzene-dihydrido-triphenylphosphine-ruthenium(II) (82498-42-8)

Guidance literature:

With Na[AlH₂(OC₂H₄OMe)2]; In toluene; benzene; a benzene soln. of Ru-complex was treated with a 70% toluene soln. of NaAlH2(OC2H4OMe)2 under inert atmosphere, mixt. was stirred for 15 min; water was added, benzene layer sepd., filtered through Celite, evapd. in vacuo, resdiue was dissolved in hexane, cooled to -78°C, crystals were collected; elem. anal.;

DOI:10.1016/S0022-328X(00)84330-2

Reference yield:

(η(6)-C6Me6)Ru(Me)2(PPh3) → hexamethylbenzene-dihydrido-triphenylphosphine-ruthenium(II) (82498-42-8)

Guidance literature:

With hydrogen; In diethyl ether; no reaction at room temp.;

DOI:10.1016/S0022-328X(00)84330-2

Reference yield:

(η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II) (82498-46-2) → hexamethylbenzene-dihydrido-triphenylphosphine-ruthenium(II) (82498-42-8) + RuHClC6(CH3)6P(C6H5)3 (75182-14-8)

Guidance literature:

With Na[AlH₂(OC₂H₄OMe)2]; In toluene; an excess of reducing agent was used, mixt. was stirred for 4 d at roomtemp.;

DOI:10.1016/S0022-328X(00)84330-2

upstream raw materials:

(η6-C6Me6)Ru(OCOCF3)2(PPh3)

(η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II)

Downstream raw materials:

hexamethylbenzene-trishydrido-triphenylphosphine-ruthenium(IV)-hexafluorophosphate

(C₆(CH₃)6)(P(C₆H₅)3)RuI₂