[NEt3H][Ga(PPh(2-SC6H4)2-κ3-S,S',P)(PPh(2-SC6H4)2-κ2-S,S')]

Base Information

Chemical Name:[NEt3H][Ga(PPh(2-SC6H4)2-κ3-S,S',P)(PPh(2-SC6H4)2-κ2-S,S')]
CAS No.:1188447-64-4
Molecular Formula:C₆H₁₆N*C₃₆H₂₆GaP₂S₄
Molecular Weight:820.737
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [NEt3H][Ga(PPh(2-SC6H4)2-κ3-S,S',P)(PPh(2-SC6H4)2-κ2-S,S')]

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Technology Process of [NEt3H][Ga(PPh(2-SC6H4)2-κ3-S,S',P)(PPh(2-SC6H4)2-κ2-S,S')]

There total 1 articles about [NEt3H][Ga(PPh(2-SC6H4)2-κ3-S,S',P)(PPh(2-SC6H4)2-κ2-S,S')] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 13450-90-3
Gallium trichloride

: 119327-18-3
bis(phenyl-2-thiol)phenylphosphine

: 121-44-8
triethylamine

: 1188447-64-4
[NEt3H][Ga(PPh(2-SC6H4)2-κ3-S,S',P)(PPh(2-SC6H4)2-κ2-S,S')]

Guidance literature:: In methanol; under dry N2; at room temp. soln. of ligand and NEt3 was slowly added dropwise to soln. of freshly sublimed GaCl3 (1:1 and 2:1 ratios), mixt. was stirred at room temp. for 22 h; ppt. was sepd. by filtration, washed with hexane, dried in vac.; elem. anal.;
DOI:10.1039/b907668a

Reference yield: 60.0%

: 1188447-64-4
[NEt3H][Ga(PPh(2-SC6H4)2-κ3-S,S',P)(PPh(2-SC6H4)2-κ2-S,S')]

: 2001-45-8
tetraphenyl phosphonium chloride

: 1188447-66-6
[PPh4][Ga(PPh(2-SC6H4)2-κ3-S,S',P)(PPh(2-SC6H4)2-κ2-S,S')]

Guidance literature:: In methanol; under dry N2; soln. of PPh4Cl was added dropwise over 20 min to suspn. of complex, suspn. was heated to reflux for 1 h and then stirred overnight at room temp.; ppt. was isolated by filtration, dried in vac.; elem. anal.;
DOI:10.1039/b907668a