Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl} [(2R)-(-)-1-(4-Methoxyphenyl)- 1 (4-Methoxyphenyl-kC)-3- Methyl-1,2-butanediaMine]rutheniuM(II) (R)-RUCY XylBINAP

Base Information

• Chemical Name: Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl} [(2R)-(-)-1-(4-Methoxyphenyl)- 1 (4-Methoxyphenyl-kC)-3- Methyl-1,2-butanediaMine]rutheniuM(II) (R)-RUCY XylBINAP
• CAS No.: 1384974-38-2
• Molecular Formula: C₇₁H₇₃ClN₂O₂P₂Ru
• Molecular Weight: 1184.84
• Mol file: 1384974-38-2.mol

Synonyms:

Chemical Property of Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl} [(2R)-(-)-1-(4-Methoxyphenyl)- 1 (4-Methoxyphenyl-kC)-3- Methyl-1,2-butanediaMine]rutheniuM(II) (R)-RUCY XylBINAP

Chemical Property:

• Sensitive.: air sensitive

Purity/Quality:

98%,99%, ^*data from raw suppliers

(R)-RUCY(regR)-XylBINAP ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl} [(2R)-(-)-1-(4-Methoxyphenyl)- 1 (4-Methoxyphenyl-kC)-3- Methyl-1,2-butanediaMine]rutheniuM(II) (R)-RUCY XylBINAP

There total 1 articles about Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl} [(2R)-(-)-1-(4-Methoxyphenyl)- 1 (4-Methoxyphenyl-kC)-3- Methyl-1,2-butanediaMine]rutheniuM(II) (R)-RUCY XylBINAP which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[RuCl(p-cymene)((S)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl)]Cl + (S)-1-isopropyl-2,2-bis(4-methoxyphenyl)ethylenediamine (148369-91-9) → RuCl[(S)-1-isopropyl-2,2-bis(4-methoxyphenyl)ethylenediamine][(S)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl] (1312713-89-5,1384974-38-2,1486548-18-8)

Guidance literature:

With diethylamine; In methanol; at 60 ℃; for 3h;

Reference yield: 97.0%

silver(I) hexafluorophosphate (26042-63-7) + RuCl[(S)-1-isopropyl-2,2-bis(4-methoxyphenyl)ethylenediamine][(S)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl] (1312713-89-5,1384974-38-2,1486548-18-8) → {Ru[(S)-1-isopropyl-2,2-bis(4-methoxyphenyl)ethylenediamine][(S)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl]}PF6

Guidance literature:

In dichloromethane; at 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

Reference yield: 95.0%

silver tetrafluoroborate (14104-20-2) + RuCl[(S)-1-isopropyl-2,2-bis(4-methoxyphenyl)ethylenediamine][(S)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl] (1312713-89-5,1384974-38-2,1486548-18-8) → {Ru[(S)-1-isopropyl-2,2-bis(4-methoxyphenyl)ethylenediamine][(S)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl]}BF4

Guidance literature:

In dichloromethane; at 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

upstream raw materials:

(S)-1-isopropyl-2,2-bis(4-methoxyphenyl)ethylenediamine

Refernces