[Pd(1,1'-bis(diphenylphosphino)ferrocene)(CH₂CH₂C(O)CH₃)](OTf)

Base Information

Chemical Name:[Pd(1,1'-bis(diphenylphosphino)ferrocene)(CH₂CH₂C(O)CH₃)](OTf)
CAS No.:560109-48-0
Molecular Formula:CF₃O₃S*C₃₈H₃₅FeOP₂Pd
Molecular Weight:880.98
Hs Code.:

[Pd(1,1'-bis(diphenylphosphino)ferrocene)(CH<sub>2</sub>CH<sub>2</sub>C(O)CH<sub>3</sub>)](OTf)

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Chemical Property of [Pd(1,1'-bis(diphenylphosphino)ferrocene)(CH₂CH₂C(O)CH₃)](OTf)

Chemical Property:

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Technology Process of [Pd(1,1'-bis(diphenylphosphino)ferrocene)(CH₂CH₂C(O)CH₃)](OTf)

There total 1 articles about [Pd(1,1'-bis(diphenylphosphino)ferrocene)(CH₂CH₂C(O)CH₃)](OTf) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 139168-18-6
[Pd(1,1'-bis(diphenylphosphino)ferrocene)(Me)(NCMe)](OTf)

: 74-85-1
ethene

: 201230-82-2
carbon monoxide

: 560109-48-0
[Pd(1,1'-bis(diphenylphosphino)ferrocene)(CH₂CH₂C(O)CH₃)](OTf)

Guidance literature:: In dichloromethane; (N2); using Schlenk techniques; bubbling of CO stream (1 bar) through soln. of (Pd(Me)(NCMe)(dppf))(OTf) in CH2Cl2 at -60°C for 10 min; then bubbling of ethene (1 bar) for 1 min, warming to -20°C for 20min; evapn. of solvent at -20°C, washing with cold diethyl ether and n-pentane, elem. anal.;
DOI:10.1021/om021049b

Reference yield:

: 560109-48-0
[Pd(1,1'-bis(diphenylphosphino)ferrocene)(CH₂CH₂C(O)CH₃)](OTf)

: 201230-82-2
carbon monoxide

: 560109-52-6
[Pd(1,1'-bis(diphenylphosphino)ferrocene)(CO)(COCH₂CH₂COCH₃)](OTf)

Guidance literature:: In dichloromethane-d2; (N2); using Schlenk techniques; maintaining of soln. of (Pd(CH2CH2C(O)CH3)(dppf))(OTf) in CD2Cl2 under a stream of CO (1 bar) at -40°C for 15 min; transferring into NMR tube at -40°C; monitoring by NMR;
DOI:10.1021/om021049b

Reference yield:

: 74-85-1
ethene

: 560109-48-0
[Pd(1,1'-bis(diphenylphosphino)ferrocene)(CH₂CH₂C(O)CH₃)](OTf)

: 201230-82-2
carbon monoxide

: 560109-57-1
[Pd(1,1'-bis(diphenylphosphino)ferrocene)(CH₂CH₂C(O)CH₂CH₂COCH₃)](OTf)

: [Pd(1,1'-bis(diphenylphosphino)ferrocene)(CH₂CH₂C(O)(CH₂CH₂CO)2CH₃)](OTf)

Guidance literature:: In dichloromethane-d2; (N2); using Schlenk techniques; treatment of soln. of (Pd(dppf)(C2H4COCH3)OTf/CD2Cl2 with CO at -40°C, bubbling of C2H4 (1 bar) through soln. of (Pd(CO)(COC2H4COCH3)(dppf))OTf in CD2Cl2 at -60°C; transferring into NMR tube at -20°C; monitoring by NMR;
DOI:10.1021/om021049b