Triphenylgermanol

Base Information

• Chemical Name: Triphenylgermanol
• CAS No.: 1529-27-7
• Molecular Formula: C18H16 Ge O
• Molecular Weight: 320.914
• NSC Number: 372807
• Nikkaji Number: J722.651I
• Mol file: 1529-27-7.mol

Synonyms:Triphenylgermanol;1529-27-7;NSC372807;triphenylgermanium hydroxide;SCHEMBL5576285;AKOS024338579;NSC-372807

Chemical Property of Triphenylgermanol

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 323.0491179
• Heavy Atom Count: 20
• Complexity: 207

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Ge](C2=CC=CC=C2)C3=CC=CC=C3.O

Technology Process of Triphenylgermanol

There total 16 articles about Triphenylgermanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

tetra-n-butylammonium hydroxide + triphenylgermanium bromide (3005-32-1) → Triphenylgermanol (1529-27-7)

Guidance literature:

In methanol; diethyl ether; 2M Bu4NOH soln. in MeOH added to Et2O soln. of Ph3GeBr (0.586 mmol), stirred at 25°C for 30 min; solvent removed under vac., chromd. (silica gel, hexane/CH2Cl2 (1:1)); mass-spect., NMR;

DOI:10.1016/j.jorganchem.2011.03.008

Reference yield: 60.0%

Ph3GeCo(CO)4 (64023-44-5,16560-95-5,30406-47-4) → Triphenylgermanol (1529-27-7)

Guidance literature:

With water; In diethyl ether; Co-complex was reacted with H2O in ether for 3 d;

DOI:10.1016/S0022-328X(00)82934-4

Reference yield: 50.0%

triphenylgermanium fluoride (379-47-5) → triphenylgermane (2816-43-5) + hexaphenyldigermane (2816-39-9) + Triphenylgermanol (1529-27-7) + bis(triphenylgermyl)oxide (2181-40-0)

Guidance literature:

In 1,2-dimethoxyethane; Electrolysis; (N2); potential controlled electrolysis at -2,2 V (vs. AgI/Ag referenceelectrode) of soln. of Ge compd. at room temp.; filtered soln. was evapd. in vac., residue was extd. with ether and solvent removed, residue was sepd. by TLC, products were identified by m. p., IR, NMR and MAS;

DOI:10.1016/S0022-328X(00)83697-9

upstream raw materials:

water

chlorotriphenylgermane

(C₆H₅)B(OGe(C₆H₅)3)2

triphenylgermanium fluoride

Downstream raw materials:

bis(triphenylgermyl)oxide

methyl-bis(triphenylgermoxy)stibane

phenyl-bis(triphenylgermoxy)stibane

Os3(CO)10(μ-η2-OCOGePh3)(μ-OMe)

Refernces

• 1、 Adams, Richard D.,Chen, Mingwei,Trufan, Eszter. "Complexes containing bridging tin- and germanium-substituted metallocarboxylate ligands from the reactions of Ph3SnOH and Ph 3GeOH with Os3(CO)12 in the presence of base". . p. 2894 - 2898. Retrieved 2011.
• 2、 Corriu, R. J. P.,Dabosi, G.,Martineau, M.. "ELECTROCHEMICAL REDUCTION OF TRIORGANOHALO-SILANES AND -GERMANES". . p. 63 - 72. Retrieved 2007/10/02.