[Rh(η2-O2CC(CH3)3)(P(C3H7)(C6H5)2)2]

Base Information

• Chemical Name: [Rh(η2-O2CC(CH3)3)(P(C3H7)(C6H5)2)2]
• CAS No.: 170300-04-6
• Molecular Formula: C₃₅H₄₃O₂P₂Rh
• Molecular Weight: 660.578
• Mol file: 170300-04-6.mol

Synonyms:

Chemical Property of [Rh(η2-O2CC(CH3)3)(P(C3H7)(C6H5)2)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Rh(η2-O2CC(CH3)3)(P(C3H7)(C6H5)2)2]

There total 1 articles about [Rh(η2-O2CC(CH3)3)(P(C3H7)(C6H5)2)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[((C6H5)2P(CH(CH3)2))2RhCl]2 (458560-65-1) → [Rh(η2-O2CC(CH3)3)(P(C3H7)(C6H5)2)2] (170300-04-6)

Guidance literature:

Multi-step reaction with 2 steps

1: not given

2: benzene

In benzene;

DOI:10.1002/1099-0682(200206)2002:6<1377::aid-ejic1377>3.0.co;2-d

Reference yield: 88.0%

[Rh(η2-O2CC(CH3)3)(P(C3H7)(C6H5)2)2] (170300-04-6) + hydrogen (1333-74-0) → [(κ(2)-O2CC(CH3)3)RhH2(PPh2(Pr-i))2] (458560-84-4)

Guidance literature:

In dichloromethane; slow stream of H2 was introduced into CH2Cl2 soln. of Rh-complex at roomtemp. for 5 min; solvent was removed in vac., solid was twice washed acetone (0 °C), dried, elem. anal.;

DOI:10.1002/1099-0682(200206)2002:6<1377::aid-ejic1377>3.0.co;2-d

Reference yield: 86.0%

[Rh(η2-O2CC(CH3)3)(P(C3H7)(C6H5)2)2] (170300-04-6) + dimethyl acetylenedicarboxylate (762-42-5) → trans-[Rh(κ(1)-O2CC(CH3)3)(η(2)-C2(CO2Me)2)(P(i-Pr)Ph2)2 (458560-97-9)

Guidance literature:

In benzene; under Ar, 1 equiv. of acetylene-compd. was added dropwise to benzene soln. of Rh-compd. at room temp. during stirring; solvent was evapd. in vac., residue was dissolved in hexane, soln. was stored at -78 °C for 12 h, solid was washed twice pentane, dried in vac., elem. anal.;

DOI:10.1002/1099-0682(200206)2002:6<1377::aid-ejic1377>3.0.co;2-d

upstream raw materials:

[((C₆H₅)2P(CH(CH₃)2))2RhCl]2

Downstream raw materials:

[Rh(κ(2)-O2CC(CH3)3)(CCPh)(C(Ph)CH2)(PPh2(Pr-i))2]

trans-[Rh(κ(1)-O2CC(CH3)3)(η(2)-C2(CO2Me)2)(P(i-Pr)Ph2)2

[(κ(2)-O2CC(CH3)3)RhH2(PPh2(Pr-i))2]

trans-[Rh(κ(1)-O2CC(CH3)3)(η(2)-MeCCCO2Me)(P(i-Pr)Ph2)2