Technology Process of (CO)3Fe(C(OCH2CH3)CHCOCOC6H5)((CH3)3CS)Fe(CO)3
There total 2 articles about (CO)3Fe(C(OCH2CH3)CHCOCOC6H5)((CH3)3CS)Fe(CO)3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
n-BuLi;
In
tetrahydrofuran;
under N2; the thiol is added to a soln. of Fe3(CO)12 in THF at -78°C, followed by n-BuLi, stirred for 10 min, warmed to room temp., thenethoxyacetylene is added, stirred for 30 min, the acyl chloride is added, stirred for 3.5 h; the solvent is removed in vac., the solid is filtd., chromd., elem. anal.;
- Guidance literature:
-
In
tetrahydrofuran; hexane;
ethoxyacetylene was added via syringe to a soln. of prepared in situ Li-complex at room temp., stirred for 30 min, then benzoyl chloride was added, the mixt. was stirred for 3.5 h, solvent was removed in vacuo; identified by NMR spectrum;
DOI:10.1021/om00151a036
