Methyl N,N-dibenzylcarbamate

Base Information

• Chemical Name: Methyl N,N-dibenzylcarbamate
• CAS No.: 102276-52-8
• Molecular Formula: C16H17NO2
• Molecular Weight: 255.316
• DSSTox Substance ID: DTXSID80394510
• Nikkaji Number: J1.742.550A
• Wikidata: Q82193942
• Mol file: 102276-52-8.mol

Synonyms:Methyl N,N-dibenzylcarbamate;102276-52-8;methyl dibenzylcarbamate;Carbamic acid, bis(phenylmethyl)-, methyl ester (9CI);SCHEMBL4018145;DTXSID80394510;Dibenzylcarbamic acid methyl ester;ADAL1039372;STK448748;AKOS003275298;AS-69442;D92827

Chemical Property of Methyl N,N-dibenzylcarbamate

Chemical Property:

• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 255.125928785
• Heavy Atom Count: 19
• Complexity: 248

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)N(CC1=CC=CC=C1)CC2=CC=CC=C2

Technology Process of Methyl N,N-dibenzylcarbamate

There total 6 articles about Methyl N,N-dibenzylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

→ methyl N,N-dibenzylcarbamate (102276-52-8)

Guidance literature:

With formic acid; 4-methoxy-N-(1-(naphthalen-2-yl)ethylidene)aniline; sodium formate; In water; at 80 ℃; for 2h; pH=4.8; Inert atmosphere;

Reference yield: 78.0%

carbon dioxide (124-38-9,18923-20-1) + dibenzylamine (103-49-1) + diazomethyl-trimethyl-silane (18107-18-1) → methyl N,N-dibenzylcarbamate (102276-52-8)

Guidance literature:

In methanol; benzene; at 20 ℃; atmospheric pressure;

DOI:10.1016/j.tet.2005.09.116

Reference yield: 63.0%

methanol (67-56-1) + N,N-dibenzylcarbamoyl fluoride → methyl N,N-dibenzylcarbamate (102276-52-8)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; at 80 ℃; for 16h;

DOI:10.1002/adsc.201600308

upstream raw materials:

methyl chloroformate

dibenzylamine

carbon dioxide

diazomethyl-trimethyl-silane

Downstream raw materials:

dibenzylamine