((1S,4R)-4-Aminocyclopent-2-en-1-yl)methanol

Base Information Edit

Chemical Name:((1S,4R)-4-Aminocyclopent-2-en-1-yl)methanol
CAS No.:122624-72-0
Molecular Formula:C₆H₁₁NO
Molecular Weight:113.159
Hs Code.:
European Community (EC) Number:603-966-7
UNII:VHC6S7P47T
DSSTox Substance ID:DTXSID001015727,DTXSID401015729
Nikkaji Number:J517.438D
Mol file:122624-72-0.mol

Synonyms:136522-35-5;((1S,4R)-4-Aminocyclopent-2-en-1-yl)methanol;(1S-cis)-4-Amino-2-cyclopentene-1-methanol;(1S,4R)-4-amino-2-cyclopentene-1-methanol;2-Cyclopentene-1-methanol, 4-amino-, (1S,4R)-;[(1S,4R)-4-AMINOCYCLOPENT-2-EN-1-YL]METHANOL;(1S,4R)-cis-4-Amino-2-cyclopentene-1-methanol;VHC6S7P47T;2,3,6-Trifluorobenzylchloride;SCHEMBL2908496;UXKZFJDNFBNQHE-RITPCOANSA-N;DTXSID001015727;DTXSID401015729;AMY14944;MFCD09953781;AKOS006277618;CS-T-02331;AC-24290;3beta-Amino-4-cyclopentene-1beta-methanol;CS-0376813;(+/-)-cis-4-amino-2-cyclopentene-1-methanol;(1S, cis)-4-amino-2-cyclopentene-1-methanol;[(1S,4R)-4-Amino-2-cyclopenten-1-yl]methanol;(-)-(1S, 4R)-4amino-2-cyclopentene-1-methanol;(-)-(1S,4R)-4-amino-2-cyclopentene-1-methanol;(1R,4S)-1-amino-4-hydroxymethyl-2-cyclopentene;(-)-(1S, 4R)-4-amino-2-cyclopentene-1-methanol;(1R,4S)-1-amino-4-(hydroxymethyl)-2-cyclopentene;(1S,4R)-(-)-4-Amino-2-cyclopentene-1-methanol;J-650016;(1R, 4S)-1-amino-4-(hydroxymethyl)-2-cyclopentene

Suppliers and Price of ((1S,4R)-4-Aminocyclopent-2-en-1-yl)methanol

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of ((1S,4R)-4-Aminocyclopent-2-en-1-yl)methanol Edit

Chemical Property:

XLogP3:-0.5
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:113.084063974
Heavy Atom Count:8
Complexity:101

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1C(C=CC1N)CO
Isomeric SMILES:C1[C@@H](C=C[C@@H]1N)CO

Technology Process of ((1S,4R)-4-Aminocyclopent-2-en-1-yl)methanol

There total 17 articles about ((1S,4R)-4-Aminocyclopent-2-en-1-yl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 132243-27-7
cis-4-hydroxymethyl-1-ureidocyclopent-2-ene

: 121481-90-1,122624-72-0,131320-53-1,136522-30-0,136522-35-5
(+/-)-cis-(4-hydroxymethyl)cyclopent-2-en-1-ylamine

Guidance literature:: With hydrogenchloride; sodium nitrate; at 0 ℃; for 1.5h;
DOI:10.1248/cpb.39.1112

Reference yield:

: 25125-21-7
4-(hydroxymethyl)cyclopentene

: 121481-90-1,122624-72-0,131320-53-1,136522-30-0,136522-35-5
(+/-)-cis-(4-hydroxymethyl)cyclopent-2-en-1-ylamine

Guidance literature:: Multi-step reaction with 8 steps

1: 82 percent / pyridine / 0 - 20 °C

2: m-CPBA / CH₂Cl₂ / -78 - 0 °C

3: 98 percent / LiN₃, (NH₄)SO₄ / ethanol; H₂O / Heating

4: 76 percent / Et₃N / CH₂Cl₂

5: 34 percent / DBU / tetrahydrofuran / Heating

6: 1,3-propanedithiol, Et₃N

7: pyridine

8: Ba(OH)2 / H₂O / Heating

With pyridine; 1.3-propanedithiol; barium dihydroxide; lithium azide; (NH₄)SO₄; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; ethanol; dichloromethane; water;
DOI:10.1080/00397919208021133