BiCl(Co(CO)3P(C₆H₅)3)2

Base Information

Chemical Name:BiCl(Co(CO)3P(C₆H₅)3)2
CAS No.:130972-53-1
Molecular Formula:C₄₂H₃₀BiClCo₂O₆P₂
Molecular Weight:1055.06
Hs Code.:

BiCl(Co(CO)3P(C<sub>6</sub>H<sub>5</sub>)3)2

Synonyms:

Suppliers and Price of BiCl(Co(CO)3P(C₆H₅)3)2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of BiCl(Co(CO)3P(C₆H₅)3)2

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of BiCl(Co(CO)3P(C₆H₅)3)2

There total 2 articles about BiCl(Co(CO)3P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 67486-01-5
potassium tricarbonyl triphenylphosphine cobalt

: 7787-60-2
bismuth(III) chloride

: 130972-53-1
BiCl(Co(CO)3P(C₆H₅)3)2

Guidance literature:: In tetrahydrofuran; byproducts: KCl; soln. of 1 equiv of BiCl3 is added to soln. (0°C) of 2 equiv. of cobalt complex with const. stirring over 10 min, soln. is allowed to warm to room temp. and is stirred for 24 h; filtn. (Celite), evapn. in vacuo, solid is redissolved in THF over which hexane is layered, solvent diffusion over 72 h at -30°C; elem. anal.;

Reference yield:

: {bismuth tri(tricarbonyl triphenylphosphine cobalt)}

: 7787-60-2
bismuth(III) chloride

: 130972-53-1
BiCl(Co(CO)3P(C₆H₅)3)2

Guidance literature:: In tetrahydrofuran; soln. of 0.5 equiv of BiCl3 is added to soln. of 1 equiv. of tricobaltbismuth complex, react. for 15 h; filtn. (Celite), evapn. in vacuo, solid is redissolved in THF over which hexane is layered, solvent diffusion over 72 h at -30°C; elem. anal.;

Reference yield: 9.0%

: 130972-53-1
BiCl(Co(CO)3P(C₆H₅)3)2

: 7787-60-2
bismuth(III) chloride

: 130972-54-2
BiCl₂(Co(CO)3P(C₆H₅)3)

: Bi₂Co₂(CO)4(P(C₆H₅)3)2

Guidance literature:: In tetrahydrofuran; to a soln. of bismuthcobalt complex is added a soln. of equimolar amt. of BiCl3, mixt. is stirred for 15 h; filtn., evapn., extn. (CH2Cl2) yields soln. and solid; filtn. of soln., recrystn. (CH2Cl2-hexane, -30°C) yields Bi2Co2-complex; solid is washed, redissolved (THF), filtn., addn. of hexane, at -30°C solvent diffusion yields CoBiCl2-complex;