μ-[15-iodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

Base Information

Chemical Name:μ-[15-iodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)
CAS No.:220355-78-2
Molecular Formula:C₉₆H₁₀₁IN₈Zn₂
Molecular Weight:1624.6
Hs Code.:

μ-[15-iodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

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Chemical Property of μ-[15-iodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

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Technology Process of μ-[15-iodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

There total 1 articles about μ-[15-iodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 187387-16-2
μ-[10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 220355-78-2
μ-[15-iodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

Guidance literature:: With AgPF₆; In pyridine; chloroform; acetonitrile; N2 atm.; a soln. of AgPF6 in CH3CN was added at 25°C to a soln. of complex and I2 in CHCl3/pyridine 30:1, 15 min; H2O was added, the organic layer was washed with H2O, dried (Na2SO4), evapd. in vac., not purified, used as crude mixt.;
DOI:10.1002/hlca.200590144

Reference yield:

: 220355-78-2
μ-[15-iodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

: 495402-49-8
2-[3-({[(tert-butyl)(dimethyl)silyl]oxy}methyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: μ-[15-[3-([[(tert-butyl)(dimethyl)silyl]oxy]methyl)phenyl]-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

Guidance literature:: With Cs₂CO₃; H₂O; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; N2 atm.; to a soln. of complex in toluene borolane-compound, Pd(P(C6H5)3)4, Cs2CO3 and three drops of H2O were added, the mixt. was deoxygenatedby bubbling N2, heated to 140°C for 18 h, cooled to 25°C; filtered through Celite, not purified, used as crude mixt.;
DOI:10.1002/hlca.200590144