[N(E)]-2-Methyl-N-[[2,4,6-tris(1,1-dimethylethyl)phenyl]phosphinidene]-2-propanamine

Base Information

• Chemical Name: [N(E)]-2-Methyl-N-[[2,4,6-tris(1,1-dimethylethyl)phenyl]phosphinidene]-2-propanamine
• CAS No.: 95792-75-9
• Molecular Formula: C₂₂H₃₈NP
• Molecular Weight: 347.524
• DSSTox Substance ID: DTXSID901128773
• Mol file: 95792-75-9.mol

Synonyms:DTXSID901128773;[N(E)]-2-Methyl-N-[[2,4,6-tris(1,1-dimethylethyl)phenyl]phosphinidene]-2-propanamine;95792-75-9

Chemical Property of [N(E)]-2-Methyl-N-[[2,4,6-tris(1,1-dimethylethyl)phenyl]phosphinidene]-2-propanamine

Chemical Property:

• XLogP3: 7.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 347.274187214
• Heavy Atom Count: 24
• Complexity: 413

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)P=NC(C)(C)C)C(C)(C)C

Technology Process of [N(E)]-2-Methyl-N-[[2,4,6-tris(1,1-dimethylethyl)phenyl]phosphinidene]-2-propanamine

There total 1 articles about [N(E)]-2-Methyl-N-[[2,4,6-tris(1,1-dimethylethyl)phenyl]phosphinidene]-2-propanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

{bis(trimethylsilyl)amino}-(t-butylimino)phosphane (54760-90-6,95792-83-9) + 2,4,6-tri-tert-butylphenyllithium (35383-91-6) → N-tert-butylimino-λ3-2,4,6-tris-(tert-butyl)phenylphosphine (95792-75-9,98039-67-9)

Guidance literature:

In tetrahydrofuran; 1.) -78 deg C, 1 h, 2.) 20 deg C, 12 h;

Reference yield: 87.0%

N-tert-butylimino-λ3-2,4,6-tris-(tert-butyl)phenylphosphine (95792-75-9,98039-67-9) → N-tert-butyl-P-(2,4,6-tri-tert-butylphenyl)phosphinimine P-oxide (95792-76-0)

Guidance literature:

With ozone; In dichloromethane; at -78 ℃;

DOI:10.1039/c39840001692

Reference yield: 78.0%

methanol (67-56-1) + N-tert-butylimino-λ3-2,4,6-tris-(tert-butyl)phenylphosphine (95792-75-9,98039-67-9) → methyl-N-tert-butyl-P-(2,4,6-tri-tert-butylphenyl)phosphonamidite

Guidance literature:

In benzene; at 20 ℃; for 10h;

upstream raw materials:

{bis(trimethylsilyl)amino}-(t-butylimino)phosphane

2,4,6-tri-tert-butylphenyllithium

Downstream raw materials:

N-tert-butyl-P-(2,4,6-tri-tert-butylphenyl)phosphinimine P-sulfide

N-tert-butyl-P-(2,4,6-tri-tert-butylphenyl)phosphinimine P-selenide

N-tert-butyl-P-(2,4,6-tri-tert-butylphenyl)phosphinimine P-oxide

N-tert-butyl-P-(2,4,6-tri-tert-butylphenyl)phosphonamidic acid