trans-[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtCl(OH)

Base Information

Chemical Name:trans-[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtCl(OH)
CAS No.:533925-96-1
Molecular Formula:C₆₄H₁₄₇ClOP₂PtSi₁₄
Molecular Weight:1618.55
Hs Code.:

Synonyms:

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Chemical Property of trans-[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtCl(OH)

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Technology Process of trans-[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtCl(OH)

There total 5 articles about trans-[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtCl(OH) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 533925-94-9
[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtSe₂O

: 937-14-4
3-chloro-benzenecarboperoxoic acid

: 533925-96-1
trans-[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtCl(OH)

: 533925-97-2
[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtSeO₃

Guidance literature:: In dichloromethane; byproducts: BbtMe2P=O; under Ar atm. to stirred soln. (Pt(Se2O)(bbtMe2P)2) in CH2Cl2 was added at -50°C soln. mCPBA in CH2Cl2 and stirred for 4 h while being warmed up to room temp.; solvents were removed, residue was purified by silica gel column chromy.(CHCl3-Et2O 5:1) followed by preparative gel permeation liquid chromy. (CHCl3); elem. anal.;
DOI:10.1246/bcsj.76.1577

Reference yield: 51.0%

: 533925-94-9
[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtSe₂O

: 937-14-4
3-chloro-benzenecarboperoxoic acid

: 533925-96-1
trans-[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtCl(OH)

: 533925-97-2
[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtSeO₃

: [[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtSe₂O₃

: [[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtSe₂O₂

Guidance literature:: In dichloromethane; byproducts: (Me3Si)3C((Me3Si)2CH)2C6H2Me2PO; elem. anal.;
DOI:10.1246/cl.2003.170

Reference yield: 30.0%

: 75-91-2
tert.-butylhydroperoxide

: 533925-93-8
[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtS₂O

: 533925-96-1
trans-[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtCl(OH)

: 533925-95-0
[[(2,6-bis(bis(dimethylsilyl)methyl)-4-[tris(trimethylsilyl)methyl]phenyl]dimethylphosphine]2PtS₂O₃

Guidance literature:: In decane; dichloromethane; byproducts: BbtMe2P=O; under Ar atm. to stirred soln. (Pt(S2O)(bbtMe2P)2) in CH2Cl2 was added dropwise at -20°C soln. TBHP in n-decane and stirred for 20 h while being warmed up to room temp.; solvents were removed, residue was purified by preparative gel liquid chromy. (CHCl3) followed by silica gel column chromy. (CHCl3); elem. anal.;
DOI:10.1246/bcsj.76.1577