Cu(N-(m-hydroxyphenylene)salicylideneaminate)2

Base Information

• Chemical Name: Cu(N-(m-hydroxyphenylene)salicylideneaminate)2
• CAS No.: 781642-03-3
• Molecular Formula: C₂₆H₂₀CuN₂O₄
• Molecular Weight: 488.002
• Mol file: 781642-03-3.mol

Synonyms:

Chemical Property of Cu(N-(m-hydroxyphenylene)salicylideneaminate)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cu(N-(m-hydroxyphenylene)salicylideneaminate)2

There total 4 articles about Cu(N-(m-hydroxyphenylene)salicylideneaminate)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

Na(salicylidene-2-aminophenol-H) + copper dichloride → Cu(N-(m-hydroxyphenylene)salicylideneaminate)2 (14706-49-1,781642-03-3,1248497-47-3)

Guidance literature:

In tetrahydrofuran; benzene; byproducts: NaCl; in moisture free atm.; to a benzene soln. of Na(saph) (1.80 mmol), a suspn. of Cu-contg. compd. (0.90 mmol) in THF was added; the mixt. was refluxed for ca. 2 h (the color changed from orange to brown); NaCl was removed by filtration and the filtrate was concd. by distn. andstripped off under reduced pressure; recrystn. in THF/benzene; elem. an al.;

Reference yield: 75.0%

2-[[(2-hydroxyphenyl)imino]methyl]phenol (1761-56-4) + copper(II) acetate monohydrate (6046-93-1) → Cu(N-(m-hydroxyphenylene)salicylideneaminate)2 (14706-49-1,781642-03-3,1248497-47-3)

Guidance literature:

In methanol; for 3h; Reflux; Inert atmosphere;

DOI:10.3390/molecules26195876

Reference yield:

Cu(N-(m-hydroxyphenylene)salicylideneaminate)2*2EtOH → Cu(N-(m-hydroxyphenylene)salicylideneaminate)2 (14706-49-1,781642-03-3,1248497-47-3)

Guidance literature:

With CH₂Cl₂; In neat (no solvent, solid phase); heating up to 120 °C in vac., then the amorphous sample was contacted with CH2Cl2 vapor;

DOI:10.1246/cl.2008.78

upstream raw materials:

bis-salicylaldehyde copper(II)

ethanol

m-Hydroxyaniline

2-[[(2-hydroxyphenyl)imino]methyl]phenol