[RuCl(tris(2-dicyclohexylphosphinoethyl)phosphine)][BPh₄]

Base Information

Chemical Name:[RuCl(tris(2-dicyclohexylphosphinoethyl)phosphine)][BPh₄]
CAS No.:146816-56-0
Molecular Formula:C₂₄H₂₀B*C₄₂H₇₈ClP₄Ru
Molecular Weight:1162.73
Hs Code.:

[RuCl(tris(2-dicyclohexylphosphinoethyl)phosphine)][BPh<sub>4</sub>]

Synonyms:

Suppliers and Price of [RuCl(tris(2-dicyclohexylphosphinoethyl)phosphine)][BPh₄]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [RuCl(tris(2-dicyclohexylphosphinoethyl)phosphine)][BPh₄]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [RuCl(tris(2-dicyclohexylphosphinoethyl)phosphine)][BPh₄]

There total 1 articles about [RuCl(tris(2-dicyclohexylphosphinoethyl)phosphine)][BPh₄] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: 146337-60-2
tris(2-(dicyclohexylphosphanyl)ethyl)phosphane

: 143-66-8
sodium tetraphenyl borate

: 146816-56-0
[RuCl(tris(2-dicyclohexylphosphinoethyl)phosphine)][BPh₄]

Guidance literature:: In methanol; dichloromethane; a mixt. of P(C2H4P(C6H11)2)3 and RuCl2(PPh3)3 in CH2Cl2 was stirred at room temp. for 10 min; addn. of NaB(C6H5)4 in CH3OH; performed under Ar using Schlenk technique;; concn.; the ppt. was filtered off, washed with CH3OH and Et2O, and dried under vac.;;
DOI:10.1021/om00027a046

Reference yield: 65.0%

: 16940-66-2
sodium tetrahydroborate

: 146816-56-0
[RuCl(tris(2-dicyclohexylphosphinoethyl)phosphine)][BPh₄]

: 1333-74-0
hydrogen

: 146816-60-6
{RuH(H₂)(P(CH₂CH₂P(C₆H₁₁)2)3)}⁽¹⁺⁾*{B(C₆H₅)4}^(1-)={RuH(H₂)(P(C₂H₄P(C₆H₁₁)2)3)}{B(C₆H₅)4}

Guidance literature:: In tetrahydrofuran; ethanol; addn. of NaBH4 to a soln. of (RuCl(P(C2H4P(C6H11)2)3))BPh4 in ethanol/THF under an atm. of H2; stirring for about 0.5 h;; removal of solvent; addn. of ethanol to the residue and stirring for at room temp. for 0.5 h; the ppt. was filtered off, washed with ethanol, and dried under vac.;;
DOI:10.1021/om00027a046