rhenium oxytetrachloride

Base Information

• Chemical Name: rhenium oxytetrachloride
• CAS No.: 204864-46-0
• Molecular Formula: Cl₄ORe
• Molecular Weight: 344.018
• Mol file: 204864-46-0.mol

Synonyms:

Chemical Property of rhenium oxytetrachloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of rhenium oxytetrachloride

There total 17 articles about rhenium oxytetrachloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

rhenium(V) chloride (13596-35-5) + oxygen (80937-33-3) → chlorotrioxorhenium + rhenium oxytetrachloride (13814-76-1,204864-46-0)

Guidance literature:

250°C, under (N2), 1 atm; destn., vacuum line;

DOI:10.1039/DT9800002467

Reference yield: 40.0%

rhenium(IV) sulfide (12038-63-0) → chlorotrioxorhenium + rhenium oxytetrachloride (204864-46-0,13814-76-1)

Guidance literature:

With oxygen; chlorine; In neat (no solvent); Cl2 : O2 = 1:3;;

Reference yield: 31.0%

aluminium trichloride (7446-70-0) + chlorotrioxorhenium → (rhenium trichloride dioxide)2 + rhenium oxytetrachloride (13814-76-1,204864-46-0)

Guidance literature:

In neat (no solvent); ReOCl3 combined with AlCl3; after 30 min transferred under vac. at -196°C into trap; CFCl3 condensed onto mixt.; slowly cooled to -78°C; elem. anal.;

DOI:10.1002/anie.200504468

upstream raw materials:

rhenium(V) chloride

oxygen

boron trichloride

aluminium trichloride

Downstream raw materials:

tetramesityloxorhenium(VI)

trans-tetraphenoxobis(trimethylphosphine)rhenium(IV)

Refernces

• 1、 Edwards, Peter G.,Wilkinson, Geoffrey,Hursthouse, Michael B.,Malik, K. M. Abdul. "IMPROVED SYNTHESES OF TETRACHLORO-OXORHENIUM(VI) AND CHLOROTRIOXORHENIUM(VII). SYNTHESIS OF ALKOXO- AND DIALKYLAMIDO-RHENIUM COMPOUNDS. THE CRYSTAL AND MOLECULAR STRUCTURES OF DI-μ-METHOXOTETRAMETHOXO-μ-OXO-DIOXODIRHENIUM(VI) (Re-Re), BIS . p. 2467 - 2475. Retrieved 2007/10/02.