(.eta5-(C6H5)2PC5H4)Fe(η5-(CH=CH2)C5H4)

Base Information

Chemical Name:(.eta5-(C6H5)2PC5H4)Fe(η5-(CH=CH2)C5H4)
CAS No.:85150-24-9
Molecular Formula:C₂₄H₂₁FeP
Molecular Weight:396.251
Hs Code.:

Synonyms:

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Chemical Property of (.eta5-(C6H5)2PC5H4)Fe(η5-(CH=CH2)C5H4)

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Technology Process of (.eta5-(C6H5)2PC5H4)Fe(η5-(CH=CH2)C5H4)

There total 1 articles about (.eta5-(C6H5)2PC5H4)Fe(η5-(CH=CH2)C5H4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 85150-23-8
1-(α-hydroxyethyl)-1'-diphenylphosphinoferrocene

: 124-40-3
dimethyl amine

: 85150-24-9
(.eta5-(C6H5)2PC5H4)Fe(η5-(CH=CH2)C5H4)

: 85150-25-0,103948-69-2
(.eta5-(C6H5)2PC5H4)Fe(η5-(CH3C(H)NMe2)C5H4)

Guidance literature:: With hydrogen bromide; In benzene; under N2 atm. slowly bubbled through stirred soln. (η5-(C6H5)2PC5H4)Fe(η5-CH3C(H)OHC5H4) in benzene, excess HNMe2 added dropwise; ppt. filtered, soln. treated with Et2O, ppt. filtered off, solvent volume reduced, oil chromed. on alumina, eluited with 50/50 hexane/ether mixt., poduct recrystd. from chloroform/ether; elem. anal.;

Reference yield: 83.0%

: 15321-51-4
diiron nonacarbonyl

: 85150-24-9
(.eta5-(C6H5)2PC5H4)Fe(η5-(CH=CH2)C5H4)

: 1006375-16-1
tetracarbonyl-[1-(diphenylphosphanyl-κP)-1'-vinylferrocene]iron(0)

Guidance literature:: In toluene; (Ar); mixt. of Fe2(CO)9 and Fe-PPh2 complex in toluene was refluxed for 1 h; cooled to room temp.; passed through silica gel with toluene; evapd. (vac.); dissolved in hot heptane; hot filtered; crystd. at room temp. and 0°C overnight; isolated by suction; washed (cold pentane); dried (vac.);
DOI:10.1016/j.jorganchem.2007.10.056

Reference yield: 75.0%

: 12129-70-3
carbonyhltungsten⁽⁰⁾(cycloocta-1,5-diene)

: 85150-24-9
(.eta5-(C6H5)2PC5H4)Fe(η5-(CH=CH2)C5H4)

: pentacarbonyl[1-(diphenylphosphanyl-κP)-1'-vinylferrocene]tungsten(0)

: trans-tetracarbonylbis[1-(diphenylphosphanyl-κP)-1'-vinylferrocene]tungsten(0)

Guidance literature:: In toluene; (Ar); soln. of W complex and Fe complex in toluene was refluxed for 3 h; cooled to room temp.; filtered through silica gel with toluene; concd. (vac.); dissolved in hot heptane; hot filtered; crystd. at room temp. and0°C; filtered; washed (hexane); dried (vac.);
DOI:10.1016/j.jorganchem.2007.10.056