[bis(triphenylphosphoranylidene)ammonium][Fe(nitrosyl)2(acetate)2]

Base Information

Chemical Name:[bis(triphenylphosphoranylidene)ammonium][Fe(nitrosyl)2(acetate)2]
CAS No.:1223627-91-5
Molecular Formula:C₄H₆FeN₂O₆*C₃₆H₃₀NP₂
Molecular Weight:772.537
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [bis(triphenylphosphoranylidene)ammonium][Fe(nitrosyl)2(acetate)2]

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Technology Process of [bis(triphenylphosphoranylidene)ammonium][Fe(nitrosyl)2(acetate)2]

There total 2 articles about [bis(triphenylphosphoranylidene)ammonium][Fe(nitrosyl)2(acetate)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: [bis(triphenylphosphoranylidene)ammonium][Fe(nitrito-N)(PPh₃)(NO)2]*acetonitrile*diethyl ether

: 64-19-7,77671-22-8
acetic acid

: 748781-52-4
[bis(triphenylphosphoranylidene)ammonium][Fe(nitrosyl)2(S₅)]

: 1223627-91-5
[bis(triphenylphosphoranylidene)ammonium][Fe(nitrosyl)2(acetate)2]

Guidance literature:: In tetrahydrofuran; acetonitrile; byproducts: P(C6H5)3, NO, H2O; (N2); placing small vial containing THF soln. of dinitrosyliron deriv. inside larger vial with soln. of diiron compd. in THF/CH3CN, addn. of THFsoln. of acetic acid to small vial, stirring for 12 h at room temp.; evapn. of soln. from larger vial, dissolving residue in THF, filtration through celite, addn. of hexane, isolation of ppt., IR, filtration soln.from small vial through celite, addn. of hexane, isolation of solid, el em. anal.;
DOI:10.1021/ja100849r

Reference yield:

: 758-12-3
deuteroacetic acid

: [bis(triphenylphosphoranylidene)ammonium][Fe(nitrito-N)(PPh₃)(NO)2]*acetonitrile*diethyl ether

: 1223627-91-5
[bis(triphenylphosphoranylidene)ammonium][Fe(nitrosyl)2(acetate)2]

Guidance literature:: In tetrahydrofuran; byproducts: NO, (2)H2O, (2)HHO; (N2); addn. of THF soln. of acetic acid to THF soln. of iron compd. at 0°C;
DOI:10.1021/ja100849r

Reference yield: 85.0%

: 616-47-7
1-methyl-1H-imidazole

: 1223627-91-5
[bis(triphenylphosphoranylidene)ammonium][Fe(nitrosyl)2(acetate)2]

: bis(triphenylphosphoranylidene)ammonium nitrite

: 1190714-59-0
[bis(triphenylphosphoranylidene)ammonium][Fe(nitrito-O)2(NO)2]

Guidance literature:: With HBF₄; In tetrahydrofuran; acetonitrile; byproducts: [N(P(C6H5)3)2]BF4; (N2); treatment of imidazole deriv. with HBF4 in THF/CH3CN at 0°C, addn. to THF suspn. of iron compd. and nitrite salt, stirring for 1 h at 0°C; filtration through celite, addn. of hexane, isolation of ppt., IR;
DOI:10.1021/ja100849r