dichlorobis(2-(m-tolylazo)pyridine)ruthenium(II)

Base Information

Chemical Name:dichlorobis(2-(m-tolylazo)pyridine)ruthenium(II)
CAS No.:77321-09-6
Molecular Formula:C₂₄H₂₂Cl₂N₆Ru
Molecular Weight:566.455
Hs Code.:

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Chemical Property of dichlorobis(2-(m-tolylazo)pyridine)ruthenium(II)

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Technology Process of dichlorobis(2-(m-tolylazo)pyridine)ruthenium(II)

There total 3 articles about dichlorobis(2-(m-tolylazo)pyridine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 14898-67-0
ruthenium(III) chloride trihydrate

: 131972-14-0
{Ag(2-(m-tolylazo)pyridine)2}ClO₄

: cis-trans-cis-dichlorobis(2-(3'-methylphenylazo)pyridine)ruthenium(II)

: 105881-11-6,648928-36-3,77321-09-6,81600-80-8,84049-23-0
trans-trans-di(Cl)bis(2-(m-tolylazo)pyridine)ruthenium(II)

: cis,cis-RuCl₂(2-(m-toylazo)pyridine)2

Guidance literature:: In methanol; byproducts: silver chloride; heating (water bath, 40°C, 15 min, Ru compd. / Ag compd. 1/1); filtration, washing (MeOH), drying (vac.), extn. (CH2Cl2, removal AgCl), crystn. (hexane), filtrates and washings concd., pptn. (H2O), drying, chromy. (silica gel, CH2Cl2/CH3CN);
DOI:10.1039/DT9910003249

Reference yield: 61.0%

: 87014-42-4
2-(3-methylphenylazo)pyridine

: 14898-67-0
ruthenium(III) chloride trihydrate

: 77321-09-6
dichlorobis(2-(m-tolylazo)pyridine)ruthenium(II)

: 77321-09-6
dichlorobis(2-(m-tolylazo)pyridine)ruthenium(II)

Guidance literature:: In methanol; N2 was passed for 15 min through soln. of RuCl3*3H2O in MeOH, soln. of ligand in MeOH was added, mixt. was heated to reflux under N2 with stirring for 8 h, cooled to room temp.; filtered, washed with H2O and Et2O, dried in vac. desiccator over P4O10, ppt. was dissolved in CHCl3, chromy. on silica gel column, eluted withCH2Cl2, evapd. at room temp.; elem. anal.; cis-complex eluted with MeCN-benzene;
DOI:10.1021/ic50221a061

Reference yield: 61.0%

: 87014-42-4
2-(3-methylphenylazo)pyridine

: 14898-67-0
ruthenium(III) chloride trihydrate

: 77321-09-6
dichlorobis(2-(m-tolylazo)pyridine)ruthenium(II)

: 77321-09-6
dichlorobis(2-(m-tolylazo)pyridine)ruthenium(II)

Guidance literature:: In methanol; N2 was passed for 15 min through soln. of RuCl3*3H2O in MeOH, soln. of ligand in MeOH was added, mixt. was heated to reflux under N2 with stirring for 8 h, cooled to room temp.; filtered, washed with H2O and Et2O, dried in vac. desiccator over P4O10, ppt. was dissolved in CHCl3, chromy. on silica gel column, eluted withCH2Cl2, evapd. at room temp.; elem. anal.; cis-complex eluted with MeCN-benzene;
DOI:10.1021/ic50221a061