2,4,6-tri-tert-butyl phenoxyl radical

Base Information

• Chemical Name: 2,4,6-tri-tert-butyl phenoxyl radical
• CAS No.: 3315-32-0
• Molecular Formula: C₁₈H₃₁O
• Molecular Weight: 263.444
• Mol file: 3315-32-0.mol

Synonyms:

Chemical Property of 2,4,6-tri-tert-butyl phenoxyl radical

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4,6-tri-tert-butyl phenoxyl radical

There total 53 articles about 2,4,6-tri-tert-butyl phenoxyl radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,4,6-tri-tert-butylphenoxol (732-26-3) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → 2,4,6-tri-tert-butylphenoxyl (3315-32-0,2525-39-5) + 3-chlorobenzoate (535-80-8)

Guidance literature:

With meso-tetraphenylporphyrin iron(III) chloride; In methanol; dichloromethane; at 25 - 30 ℃; Rate constant; Oxygen transfer to (TPP)Fe(III)(Cl) with/without buffer. Chromium complex also investigated, without TBPH and methanol;

DOI:10.1021/ja00221a029

Reference yield:

2,3-Dimethyl-2-butene (563-79-1) + 2,4,6-tri-tert-butylphenoxol (732-26-3) + 4-cyano-N,N-dimethylaniline-N-oxide (62820-00-2) → 2,3-dimethyl-2,3-epoxybutane (5076-20-0) + 2,4,6-tri-tert-butylphenoxyl (3315-32-0,2525-39-5) + 4-cyano-N-methylaniline (4714-62-9) + 4-cyano-N,N-dimethylaniline (1197-19-9)

Guidance literature:

With (2,3,7,8,12,13,17,18-octamethyl-5,10,15,20-tetraphenylporphinato)iron(III) chloride; In dichloromethane; at 25 ℃; Product distribution;

DOI:10.1021/ja00285a018

Reference yield:

Cumene hydroperoxide (80-15-9) + 2,4,6-tri-tert-butylphenoxol (732-26-3) → 2,4,6-tri-tert-butylphenoxyl (3315-32-0,2525-39-5) + 1-methyl-1-phenylethyl alcohol (617-94-7)

Guidance literature:

With meso-tetraphenylporphyrin iron(III) chloride; In methanol; dichloromethane; at 30 ℃; Rate constant; oxygen transfer to (TPP)Fe(III)(Cl) with/without buffer;

DOI:10.1021/ja00221a029

upstream raw materials:

4-bromo-2,4,6-tri-tert-butyl-2,5-cyclohexadiene-1-one

2,4,6-tri-tert-butylphenoxol

2,6-di-tert-butyl-4-tert-butoxyphenoxyl

benzene

Downstream raw materials:

4-chloro-2,4,6-tri-tert-butylcyclohexa-2,5-dienone

2,4,6-tri-tert-butyl-4-(2,4,6-tribromo-phenoxy)-cyclohexa-2,5-dienone

2,4,6-tri-tert-butyl-4-(2,4,6-triphenyl-phenoxy)-cyclohexa-2,5-dienone

2,4,6-tri-t-butyl-4-nitrocyclohexa-2,5-dien-1-one

Refernces

• 1、 Ar, Deniz,Kilpatrick, Alexander F. R.,Cula, Beatrice,Herwig, Christian,Limberg, Christian. "Transformation of Formazanate at Nickel(II) Centers to Give a Singly Reduced Nickel Complex with Azoiminate Radical Ligands and Its Reactivity toward Dioxygen". supporting information. p. 13844 - 13853. Retrieved 2021/05/04.
• 2、 Bonck, Thorsten,De Waal Malefijt, Matina Elo?se,Dobbelaar, Emiel,Kelm, Harald,Klein, Johannes E. M. N.,Krüger, Hans-J?rg,Rauber, Christian,Schmitz, Markus. "Combining Structural with Functional Model Properties in Iron Synthetic Analogue Complexes for the Active Site in Rabbit Lipoxygenase". supporting information. p. 13145 - 13155. Retrieved 2021/09/03.