[(PPh3)2Pt(μ-S(CH2)2S)RhCl(η5-C5Me5)]BF4

Base Information

• Chemical Name: [(PPh3)2Pt(μ-S(CH2)2S)RhCl(η5-C5Me5)]BF4
• CAS No.: 500199-78-0
• Molecular Formula: BF₄*C₄₈H₄₉ClP₂PtRhS₂
• Molecular Weight: 1172.24
• Mol file: 500199-78-0.mol

Synonyms:

Chemical Property of [(PPh3)2Pt(μ-S(CH2)2S)RhCl(η5-C5Me5)]BF4

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of [(PPh3)2Pt(μ-S(CH2)2S)RhCl(η5-C5Me5)]BF4

There total 1 articles about [(PPh3)2Pt(μ-S(CH2)2S)RhCl(η5-C5Me5)]BF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

silver tetrafluoroborate (14104-20-2) + dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer + cis-bis(triphenylphosphine)platinum(II) ethane-1,2-dithiolate (56213-51-5) → [(PPh3)2Pt(μ-S(CH2)2S)RhCl(η5-C5Me5)]BF4 (500199-78-0)

Guidance literature:

In tetrahydrofuran; byproducts: AgCl; under N2; AgBF4 (0.1618 mmol) was added to a soln. of Rh-contg. compd. (0.0809 mmol) in anhyd. and deoxigenated THF; stirring for 5 min at room temp.; then Pt-contg. compd. (0.1618 mmol) was added; AgCl was removed by filtration; the filtrate was concd. and the ppt. wasobtained by C6H14 addn.; the solid was filtrated, washed with C6H14 and dried under vac.; elem. anal.;

DOI:10.1016/S0022-328X(02)01925-3

upstream raw materials:

silver tetrafluoroborate

cis-bis(triphenylphosphine)platinum(II) ethane-1,2-dithiolate