mer-Mn(CO)3[P(OPh)3]2Cl

Base Information

• Chemical Name: mer-Mn(CO)3[P(OPh)3]2Cl
• CAS No.: 15526-56-4
• Molecular Formula: C₃₉H₃₀ClMnO₉P₂
• Molecular Weight: 795
• Mol file: 15526-56-4.mol

Synonyms:

Chemical Property of mer-Mn(CO)3[P(OPh)3]2Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of mer-Mn(CO)3[P(OPh)3]2Cl

There total 11 articles about mer-Mn(CO)3[P(OPh)3]2Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

triphenyl phosphite (101-02-0) + pentacarbonylchloromanganese(I) (14100-30-2) → fac-tricarbonylchlorobis(triphenylphosphite)manganese(I) (15526-56-4,79703-04-1)

Guidance literature:

In chloroform; N2-atmosphere; addn. of P(OPh)3 to soln. of Mn-complex, stirring (room temp., overnight); hexane addn., pptn. on concentration, decantation, recrystn.(CHCl3/hexane);

DOI:10.1016/S0020-1693(00)83734-2

Reference yield:

pentacarbonylchloromanganese(I) (14100-30-2) → Mn(CO)3(P(O(C6H5))3)2Cl (79703-04-1,15526-56-4) + Mn(CO)4(P(O(C6H5))3)Cl (85362-16-9)

Guidance literature:

With triphenyl phosphite; In not given; byproducts: CO; Irradiation (UV/VIS); N2 atmosphere, excess phosphine in soln., photolysis (200-W high-pressure Hg arc lamp, Corning cutoff filters, λ>250 nm); not isolated, IR detection;

Reference yield:

HMn(CO)3{P(C6H5O)3}2 (16972-18-2,16923-76-5,17250-37-2) → mer-trans-ClMn(CO)3(triphenyl phosphite)2 (15526-56-4,79703-04-1)

Guidance literature:

With tetrachloromethane; In tetrachloromethane; Irradiation (UV/VIS); under Ar, CCl4 soln. of educt irradiated with Riko 100 W high-pressure Hg lamp for 1.5 h; evapd. in vac., chromd. (Florisil, petroleum ether, cyclohexane, benzene), recrystd. from benzene-petroleum ether;

DOI:10.1246/bcsj.56.2296

upstream raw materials:

pentacarbonylchloromanganese(I)

triphenyl phosphite

HMn(CO)3{P(C₆H₅O)3}2

(CH₃)3SnMn(CO)3(P(OC₆H₅)3)2

Downstream raw materials:

(η5-1-chloroindenyl)tricarbonylmanganese(I)

(η5-1-chloroindenyl)dicarbonyl(triphenylphosphite)manganese(I)

mer-Mn(CO)3[P(OPh)3]2Cl

fac-tricarbonylchlorobis(triphenylphosphite)manganese(I)