Fe(CO)3(1,2-bis(diphenylphosphino)ethane)

Base Information

• Chemical Name: Fe(CO)3(1,2-bis(diphenylphosphino)ethane)
• CAS No.: 14881-58-4
• Molecular Formula: 3CO*C₂₆H₂₄P₂*Fe
• Molecular Weight: 538.302
• Mol file: 14881-58-4.mol

Synonyms:

Chemical Property of Fe(CO)3(1,2-bis(diphenylphosphino)ethane)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Fe(CO)3(1,2-bis(diphenylphosphino)ethane)

There total 20 articles about Fe(CO)3(1,2-bis(diphenylphosphino)ethane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → 1,2-bis(diphenylphosphino)ethaneiron(0) tricarbonyl (38894-55-2,14881-58-4)

Guidance literature:

In toluene; Irradiation (UV/VIS); irradiation (mercury high pressure lamp TQ 150) under N2 at 20°C; concn., cooling to -20°C, washing with petroleum ether and drying; second crop on concn. of mother liquor on addn. of petroleum ether;

Reference yield: 72.0%

(cyclooctatetraene)tricarbonyliron (12093-05-9) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → 1,2-bis(diphenylphosphino)ethaneiron(0) tricarbonyl (38894-55-2,14881-58-4)

Guidance literature:

In benzene; 2-120 h, reflux in equimolar proportions of educts or with excess of πC8H8Fe(CO)3;

DOI:10.1021/ic50077a019

Reference yield: 60.0%

K(1+)*H(1+)*Fe(CO)4(2-)=KHFe(CO)4 + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → 1,2-bis(diphenylphosphino)ethaneiron(0) tricarbonyl (38894-55-2,14881-58-4)

Guidance literature:

In ethanol; other Radiation; under N2; EtOH soln. of KHFe(CO)4 added to Ph2PCH2CH2PPh2; heated in microwave reactor (150 W, 5 min, 100°C, max T=112°C, max P=50psi); cooled to room temp.; ppt. collected by suction filtration; washed with H2O and EtOH; dried;

DOI:10.1021/om900821c

upstream raw materials:

triiron dodecarbonyl

1,2-bis-(diphenylphosphino)ethane

2,3-dimethyl-buta-1,3-diene

carbon monoxide

Downstream raw materials:

{Fe((C₆H₅)2PC₂H₄P(C₆H₅)2)(CO)3}⁽¹⁺⁾

{Fe(CO)3((C₆H₅)2P(CH₂)2P(C₆H₅)2)H}⁽¹⁺⁾*CF₃SO₃^(1-)={Fe(CO)3((C₆H₅)2P(CH₂)2P(C₆H₅)2)H}CF₃SO₃

[1,2-bis(diphenylphosphino)ethane]dicarbonyl(chlorodimethylsilyl)hydridoiron

[1,2-bis(diphenylphosphino)ethane]dicarbonyl(trimethylsilyl)hydridoiron