4-Octene-3,6-dione, 2,2,7,7-tetramethyl-, (4E)-

Base Information

• Chemical Name: 4-Octene-3,6-dione, 2,2,7,7-tetramethyl-, (4E)-
• CAS No.: 10507-31-0
• Molecular Formula: C12H20O2
• Molecular Weight: 196.29
• Mol file: 10507-31-0.mol

Synonyms:.2,2,7,7-Tetramethyl-oct-4t-en-3,6-dion;.2,2,7,7-tetramethyl-oct-4-en-3,6-dione;2,2,7,7-tetramethyl-oct-4t-ene-3,6-dione;

Chemical Property of 4-Octene-3,6-dione, 2,2,7,7-tetramethyl-, (4E)-

Chemical Property:

• PSA: 34.14000
• LogP: 2.77300

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-Octene-3,6-dione, 2,2,7,7-tetramethyl-, (4E)-

There total 3 articles about 4-Octene-3,6-dione, 2,2,7,7-tetramethyl-, (4E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

Nitrosobenzene (586-96-9) + (3,3-dimethyl-2-oxobutyl)triphenylbismuthonium tetrafluoroborate → triphenylbismuthane (603-33-8) + (E)-2,2,7,7-Tetramethyl-oct-4-ene-3,6-dione (10507-31-0)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; at -78 ℃;

Reference yield: 20.0%

di-tert-butylthioketene (16797-75-4) → 2,2,4,4-tetramethylpentane-3-thione S-oxide (56956-25-3) + 3,3-di-tert-butylthioketene S-oxide (16797-76-5) + (E)-2,2,7,7-Tetramethyl-oct-4-ene-3,6-dione (10507-31-0)

Guidance literature:

With oxygen; In chloroform; for 10h;

DOI:10.1039/c39810000638

Reference yield: 18.0%

di-tert-butylthioketene (16797-75-4) → 2,2,4,4-tetramethylpentane-3-thione S-oxide (56956-25-3) + 3,3-di-tert-butylthioketene S-oxide (16797-76-5) + isobutene (115-11-7,15220-85-6) + (E)-2,2,7,7-Tetramethyl-oct-4-ene-3,6-dione (10507-31-0)

Guidance literature:

With oxygen; In dichloromethane; for 20h; Ambient temperature; Irradiation; dye-sensitized oxidation;

DOI:10.1021/jo00178a007

upstream raw materials:

di-tert-butylthioketene

Nitrosobenzene

Downstream raw materials:

1-[2-Diethylamino-6-(2,2-dimethyl-propionyl)-cyclohex-3-enyl]-2,2-dimethyl-propan-1-one