C₁₃H₈(CH₂C₆H₅)CH₂CH₂C₁₃H₈(CH₂C₆H₅)

Base Information

• Chemical Name: C₁₃H₈(CH₂C₆H₅)CH₂CH₂C₁₃H₈(CH₂C₆H₅)
• CAS No.: 242793-29-9
• Molecular Formula: C₄₂H₃₄
• Molecular Weight: 538.732
• Mol file: 242793-29-9.mol

Synonyms:

Chemical Property of C₁₃H₈(CH₂C₆H₅)CH₂CH₂C₁₃H₈(CH₂C₆H₅)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₃H₈(CH₂C₆H₅)CH₂CH₂C₁₃H₈(CH₂C₆H₅)

There total 1 articles about C₁₃H₈(CH₂C₆H₅)CH₂CH₂C₁₃H₈(CH₂C₆H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-benzyl-fluorene (164728-31-8) + ethylene dibromide (106-93-4) → C13H8(CH2C6H5)CH2CH2C13H8(CH2C6H5) (242793-29-9)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; for 28h; Ambient temperature;

DOI:10.1016/S0022-328X(99)00074-1

Reference yield:

zirconium(IV) chloride (10026-11-6) + C13H8(CH2C6H5)CH2CH2C13H8(CH2C6H5) (242793-29-9) → (C13H7(CH2C6H5)CH2CH2C13H7(CH2C6H5))ZrCl2 (243145-30-4,195977-25-4,243145-25-7)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; inert atmosphere; addn. of 2 equiv. BuLi (in hexane) to ligand precursor (in Et2O), stirring (room temp., <= 4h), addn. of 1 equiv. ZrCl4, stirring (room temp., 8 h); according to soly. of product in Et2O (not specified); for sol. product, filtration over Na2SO4, crystn. (Et2O or hexane); for insol. product, filtration of reaction mixt. over Na2SO4, extn. into CH2Cl2 or PhMe, crystn. (-20 or -78.°C);

DOI:10.1016/S0022-328X(99)00074-1

upstream raw materials:

4-benzyl-fluorene

ethylene dibromide

Downstream raw materials:

(C₁₃H₇(CH₂C₆H₅)CH₂CH₂C₁₃H₇(CH₂C₆H₅))ZrCl₂