Hydroperoxide, 1-methyl-1-[6-(1-methylethyl)-2-naphthalenyl]ethyl

Base Information

• Chemical Name: Hydroperoxide, 1-methyl-1-[6-(1-methylethyl)-2-naphthalenyl]ethyl
• CAS No.: 105443-43-4
• Molecular Formula: C16H20O2
• Molecular Weight: 244.334
• DSSTox Substance ID: DTXSID40431218
• Nikkaji Number: J1.269.878J
• Wikidata: Q82245047
• Mol file: 105443-43-4.mol

Synonyms:105443-43-4;Hydroperoxide, 1-methyl-1-[6-(1-methylethyl)-2-naphthalenyl]ethyl;SCHEMBL6671217;DTXSID40431218;CDVVHSFGSFPECK-UHFFFAOYSA-N;2-(6-Isopropyl-2-naphthyl)-2-hydroperoxypropane;2-(2-hydroperoxy-2-propyl)-6-isopropylnaphthalene;2-i-propyl-6-(1-hydroperoxy-1-methylethyl)naphthalene

Chemical Property of Hydroperoxide, 1-methyl-1-[6-(1-methylethyl)-2-naphthalenyl]ethyl

Chemical Property:

• XLogP3: 4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 244.146329876
• Heavy Atom Count: 18
• Complexity: 272

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C1=CC2=C(C=C1)C=C(C=C2)C(C)(C)OO

Technology Process of Hydroperoxide, 1-methyl-1-[6-(1-methylethyl)-2-naphthalenyl]ethyl

There total 1 articles about Hydroperoxide, 1-methyl-1-[6-(1-methylethyl)-2-naphthalenyl]ethyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,6-diisopropylnaphthalene (24157-81-1) → 1-(6-(1-methylethyl)naphthalen-2-yl)ethanone (107208-69-5) + bis(1-methyl-1-(6-isopropylnaphth-2-yl)ethyl)peroxide (1234705-64-6) + 2-(1-hydroperoxy-1-methylethyl)-6-(1-methylethyl)naphthalene (105443-43-4) + 2-(2-hydroxy-2-methylethyl)-6-(2-methylethyl)naphthalene (83922-21-8)

Guidance literature:

With copper(II) choride dihydrate; tetrabutylammomium bromide; oxygen; at 80 ℃; for 10h;

DOI:10.2478/s11532-009-0134-8

Reference yield:

2-(1-hydroperoxy-1-methylethyl)-6-(1-methylethyl)naphthalene (105443-43-4) → 6-methoxy-2-acetylnaphthalene (3900-45-6) + 2-methoxy-6-(1-hydroxy-1-methylethyl)naphthalene (34352-83-5)

Guidance literature:

Multi-step reaction with 3 steps

1: sulfuric acid / acetone / Heating

2: sulfuric acid / 6 h / 79 - 82 °C

3: copper acetylacetonate; N-hydroxyphthalimide; 2,2'-azobis(isobutyronitrile) / benzonitrile / 0.83 h / 70 °C

With copper acetylacetonate; N-hydroxyphthalimide; 2,2'-azobis(isobutyronitrile); sulfuric acid; In benzonitrile; acetone;

DOI:10.1007/s00706-011-0630-3

Reference yield:

2-(1-hydroperoxy-1-methylethyl)-6-(1-methylethyl)naphthalene (105443-43-4) → 2,6-bis(2-hydroxy-2-propyl)naphthalene (24157-82-2)

Guidance literature:

Multi-step reaction with 2 steps

1: Na₂SO₃ / ethanol; H₂O / 3 h / 40 °C

2: O₂; NaOH; palmitic acid / CuCN / H₂O / 27 h / 90 °C / 760 Torr

With sodium hydroxide; oxygen; 1-hexadecylcarboxylic acid; sodium sulfite; CuCN; In ethanol; water; 1: Reduction / 2: Catalytic oxidation;

DOI:10.1002/(sici)1097-458x(200003)38:3<213::aid-mrc617>3.0.co;2-g

upstream raw materials:

2,6-diisopropylnaphthalene

Downstream raw materials:

2-(2-hydroxy-2-methylethyl)-6-(2-methylethyl)naphthalene

2,6-bis(2-hydroxy-2-propyl)naphthalene

6-methoxy-2-acetylnaphthalene

2-methoxy-6-(1-hydroxy-1-methylethyl)naphthalene

Refernces