[Pd(Me)(diphenylphosphinoacetic acid, ethyl ester-κ(2)-P,O)(PPh3)]BF4

Base Information

• Chemical Name: [Pd(Me)(diphenylphosphinoacetic acid, ethyl ester-κ(2)-P,O)(PPh3)]BF4
• CAS No.: 191540-72-4
• Molecular Formula: BF₄*C₃₅H₃₅O₂P₂Pd
• Molecular Weight: 742.834
• Mol file: 191540-72-4.mol

Synonyms:

Chemical Property of [Pd(Me)(diphenylphosphinoacetic acid, ethyl ester-κ(2)-P,O)(PPh3)]BF4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(Me)(diphenylphosphinoacetic acid, ethyl ester-κ(2)-P,O)(PPh3)]BF4

There total 1 articles about [Pd(Me)(diphenylphosphinoacetic acid, ethyl ester-κ(2)-P,O)(PPh3)]BF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

silver tetrafluoroborate (14104-20-2) + [MePd(diphenylphosphinoacetic acid, ethylester-κ(1)-P)Cl]2 (191540-75-7) + triphenylphosphine (603-35-0) → [Pd(Me)(diphenylphosphinoacetic acid, ethyl ester-κ(2)-P,O)(PPh3)]BF4 (191540-72-4)

Guidance literature:

In dichloromethane; N2-atmosphere; stirring Pd-complex with 2 equiv. of PPh3 (room temp., few min), addn. to excess of AgBF4 suspn., stirring (room temp., 5 min); filtration (Celite), solvent removal (vac.); elem. anal.;

DOI:10.1016/S0022-328X(96)06841-6

Reference yield:

[Pd(Me)(diphenylphosphinoacetic acid, ethyl ester-κ(2)-P,O)(PPh3)]BF4 (191540-72-4) + carbon monoxide (201230-82-2) → [Pd(MeCO)(diphenylphosphinoacetic acid, ethyl ester-κ(2)-P,O)(PPh3)]BF4 (191540-86-0)

Guidance literature:

In chloroform-d1; CO-atmosphere; bubbling CO through soln. of Pd-complex for 5 min; not isolated, detd. by NMR spectroscopy;

DOI:10.1016/S0022-328X(96)06841-6

upstream raw materials:

silver tetrafluoroborate

[MePd(diphenylphosphinoacetic acid, ethylester-κ(1)-P)Cl]2

triphenylphosphine

Downstream raw materials:

[Pd(MeCO)(diphenylphosphinoacetic acid, ethyl ester-κ(2)-P,O)(PPh3)]BF4