[rhodium(II)(5,10,15,20-tetratolylporphyrin)]2

Base Information

• Chemical Name: [rhodium(II)(5,10,15,20-tetratolylporphyrin)]2
• CAS No.: 103533-57-9
• Molecular Formula: C₉₆H₇₂N₈Rh₂
• Molecular Weight: 1543.49
• Mol file: 103533-57-9.mol

Synonyms:

Chemical Property of [rhodium(II)(5,10,15,20-tetratolylporphyrin)]2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [rhodium(II)(5,10,15,20-tetratolylporphyrin)]2

There total 1 articles about [rhodium(II)(5,10,15,20-tetratolylporphyrin)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

rhodium(III) tetrakis(4-tolyl)porphyrin chloride (205259-72-9) → [rhodium(II)(5,10,15,20-tetratolylporphyrin)]2 (103533-57-9)

Guidance literature:

With [2.2]paracyclophane; KOH; D₂O; In benzene-d6; (2.2)paracyclophane reacted with Rh complex, KOH and D2O in benzene-d6 at 60°C for 4 d or 120°C for 8 d; monitored by (1)H NMR spectra;

DOI:10.1021/ja3047415

Reference yield: 60.0%

(5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride (103562-44-3) + [rhodium(II)(5,10,15,20-tetratolylporphyrin)]2 (103533-57-9) → Rh(ttp)(c-octyl) (1228088-78-5) + Rh(5,10,15,20-tetratolylporphyrinato)(n-octyl) (1228088-80-9)

Guidance literature:

Rh(5,10,15,20-tetratolylporphyrin); In further solvent(s); 10:1 mixt. of rhodium and dirhodium compds. in cyclooctane heated at 120°C for 15 h under N2;

DOI:10.1021/ja101586w

Reference yield: 59.0%

tributyl-amine (102-82-9) + [rhodium(II)(5,10,15,20-tetratolylporphyrin)]2 (103533-57-9) → rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)nBu (1228390-57-5)

Guidance literature:

In further solvent(s); mixt. of Rh complex (0.0065 mmol) and nBu3N degassed (3 freeze-pump-thawcycles), heated under N2 at 120°C for 1 d; solvent evapd. in vac., residue chromd. (silica gel, hexane/CH2Cl2 eluent (1:1));

DOI:10.1016/j.jorganchem.2010.02.007

upstream raw materials:

rhodium(III) tetrakis(4-tolyl)porphyrin chloride

Downstream raw materials:

rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)ⁿBu

Rh(ttp)(c-octyl)

Rh(5,10,15,20-tetratolylporphyrinato)(n-octyl)

(5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride