Rh(tetramesitylporphyrin)CHDCO₂Et

Base Information

• Chemical Name: Rh(tetramesitylporphyrin)CHDCO₂Et
• CAS No.: 927403-46-1
• Molecular Formula: C₆₀H₅₉N₄O₂Rh
• Molecular Weight: 972.052
• Mol file: 927403-46-1.mol

Synonyms:

Chemical Property of Rh(tetramesitylporphyrin)CHDCO₂Et

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of Rh(tetramesitylporphyrin)CHDCO₂Et

There total 2 articles about Rh(tetramesitylporphyrin)CHDCO₂Et which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

diazoacetic acid ethyl ester (623-73-4) + 5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) (121393-39-3) + water-d2 (7789-20-0) → Rh(tetramesitylporphyrin)CHDCO2Et (927403-46-1)

Guidance literature:

In benzene; D2O was added to soln. Rh complex in benzene and stirred at room temp. for 15 min, ethyl diazoacetate was added and stirred at room temp. for 30min under N2 atm. in the absence of light; chromy. on silica (hexane-CH2Cl2 2:1 to 1:1);

DOI:10.1021/om060833j

Reference yield: 68.0%

diazoacetic acid ethyl ester (623-73-4) + (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride (124535-65-5) + water-d2 (7789-20-0) → Rh(tetramesitylporphyrin)CHDCO2Et (927403-46-1)

Guidance literature:

In benzene; D2O was added to soln. Rh complex in benzene and stirred at room temp. for 15 min, ethyl diazoacetate was added and stirred at room temp. for 30min under N2 atm. in the absence of light; chromy. on silica (2:1 to 1:1);

DOI:10.1021/om060833j

upstream raw materials:

diazoacetic acid ethyl ester

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)

water-d2

(5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride