MoO((C₆H₅)4C₂₀N₄H₁₀)NCS

Base Information

• Chemical Name: MoO((C₆H₅)4C₂₀N₄H₁₀)NCS
• CAS No.: 73515-84-1
• Molecular Formula: C₄₅H₃₀MoN₅OS
• Molecular Weight: 784.772
• Mol file: 73515-84-1.mol

Synonyms:

Chemical Property of MoO((C₆H₅)4C₂₀N₄H₁₀)NCS

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of MoO((C₆H₅)4C₂₀N₄H₁₀)NCS

There total 1 articles about MoO((C₆H₅)4C₂₀N₄H₁₀)NCS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethoxy-oxo-molybdenum(V) 5,10,15,20-tetraphenylporphyrin (65404-71-9) + potassium thioacyanate (333-20-0) → {oxomolybdenum(V) tetraphenylporphyrine(NCS)} (73515-84-1)

Guidance literature:

In dichloromethane; water; aq. soln. of KSCN mixed with soln. of Mo complex in CH2Cl2; evapn. of org. layer, dissolving in CH2Cl2, filtration, evapn., recrystn. (CH2Cl2-hexane); elem. anal.;

DOI:10.1246/bcsj.54.170

Reference yield:

MoO((C6H5)4C20N4H10)NCS (73515-84-1) → MoO((C6H5)4C20N4H10)((CH3)2SO)(1+)*NCS(1-)=(MoO((C6H5)4C20N4H10)((CH3)2SO))NCS (94782-06-6)

Guidance literature:

With dimethyl sulfoxide; In dichloromethane; not septd., detected by UV; Kinetics;

Reference yield:

{oxomolybdenum(V) tetraphenylporphyrine(NCS)} (73515-84-1) + superoxide-ion → (5,10,15,20-meso-tetraphenylporphyrinato)oxomolybdenum(IV) (33519-60-7)

Guidance literature:

With dimethyl sulfoxide; In dichloromethane; (Ar); a large excess of KO2 added to a soln. of Mo-complex containing DMSO at -72°C; warmed to 25°C; detected by UV;

upstream raw materials:

ethoxy-oxo-molybdenum(V) 5,10,15,20-tetraphenylporphyrin

potassium thioacyanate

Downstream raw materials:

Mo(V)O(tpp)OCH₃

(5,10,15,20-meso-tetraphenylporphyrinato)oxomolybdenum(IV)

MoO((C₆H₅)4C₂₀N₄H₁₀)((CH₃)2SO)⁽¹⁺⁾*NCS^(1-)=(MoO((C₆H₅)4C₂₀N₄H₁₀)((CH₃)2SO))NCS