4-nitrophenyl dimethylphosphinate

Base Information

• Chemical Name: 4-nitrophenyl dimethylphosphinate
• CAS No.: 13344-08-6
• Molecular Formula: C8H10 N O4 P
• Molecular Weight: 215.145
• Mol file: 13344-08-6.mol

Synonyms:Phosphinicacid, dimethyl-, 4-nitrophenyl ester (9CI); Phosphinic acid, dimethyl-,p-nitrophenyl ester (7CI,8CI); 4-Nitrophenyl dimethylphosphinate; p-Nitrophenyldimethylphosphinate

Chemical Property of 4-nitrophenyl dimethylphosphinate

Chemical Property:

• Vapor Pressure: 0.000439mmHg at 25°C
• Boiling Point: 325.3°C at 760 mmHg
• Flash Point: 150.6°C
• Density: 1.296g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-nitrophenyl dimethylphosphinate

There total 2 articles about 4-nitrophenyl dimethylphosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + dimethylphosphinic acid chloride (1111-92-8) → p-nitrophenyl dimethyl phosphinate (13344-08-6)

Guidance literature:

With pyridine; In dichloromethane;

DOI:10.1039/P29760000515

Reference yield:

→ p-nitrophenyl dimethyl phosphinate (13344-08-6)

Guidance literature:

Dimethyl-phosphinsaeurechlorid, p-Nitro-phenol;

Reference yield:

ethanol (64-17-5) + p-nitrophenyl dimethyl phosphinate (13344-08-6) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + O-ethyl(dimethyl) phosphinate (2511-19-5)

Guidance literature:

With potassium hydroxide; 18-crown-6 ether; at 25 ℃; Further Variations:; Reagents; Kinetics;

DOI:10.1039/b314886f

upstream raw materials:

4-nitro-phenol

dimethylphosphinic acid chloride

Downstream raw materials:

4-nitro-phenol

O-ethyl(dimethyl) phosphinate

C₉H₁₄NOP

C₈H₁₂NOP

Refernces

• 1、 Buncel, Erwin,Albright, Kendall G.,Onyido, Ikenna. "Nucleophilic displacement on 4-nitrophenyl dimethyl phosphinate by ethoxide ion: Alkali metal ion catalysis and mechanism". . p. 601 - 610. Retrieved 2007/10/03.