N-((1S,2R,3S,6R)-3-Methoxy-7-oxa-bicyclo[4.1.0]hept-4-en-2-yl)-4-methyl-benzenesulfonamide

Base Information

Chemical Name:N-((1S,2R,3S,6R)-3-Methoxy-7-oxa-bicyclo[4.1.0]hept-4-en-2-yl)-4-methyl-benzenesulfonamide
CAS No.:87160-99-4
Molecular Formula:C₁₄H₁₇NO₄S
Molecular Weight:295.359
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N-((1S,2R,3S,6R)-3-Methoxy-7-oxa-bicyclo[4.1.0]hept-4-en-2-yl)-4-methyl-benzenesulfonamide

Chemical Property:

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Technology Process of N-((1S,2R,3S,6R)-3-Methoxy-7-oxa-bicyclo[4.1.0]hept-4-en-2-yl)-4-methyl-benzenesulfonamide

There total 10 articles about N-((1S,2R,3S,6R)-3-Methoxy-7-oxa-bicyclo[4.1.0]hept-4-en-2-yl)-4-methyl-benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 127-65-1
chloroamine-T

: 87160-99-4
N-((1S,2R,3S,6R)-3-Methoxy-7-oxa-bicyclo[4.1.0]hept-4-en-2-yl)-4-methyl-benzenesulfonamide

Guidance literature:: Multi-step reaction with 7 steps

1: 92 percent / ZnSO₄ / methanol / 1 h / Heating

2: 5 percent KOH / 0 °C

3: acetic acid / 1 h / 80 °C

4: 60 percent / Et₃N / CH₂Cl₂ / 0.25 h / 0 °C

5: 75 percent / 1 M KOtBu / tetrahydrofuran; 2-methyl-propan-2-ol / 0.5 h / 60 °C

6: 4 percent / MeONa / methanol / Ambient temperature

7: Heating

With potassium hydroxide; potassium tert-butylate; sodium methylate; triethylamine; zinc(II) sulfate; In tetrahydrofuran; methanol; dichloromethane; acetic acid; tert-butyl alcohol;

Reference yield:

: 112346-61-9
DL-(1α,2α,3β,6β)-2-Brom-6-<(4-methylphenylsulfonyl)amino>-4-cyclohexen-1,3-diol

: 87160-99-4
N-((1S,2R,3S,6R)-3-Methoxy-7-oxa-bicyclo[4.1.0]hept-4-en-2-yl)-4-methyl-benzenesulfonamide

Guidance literature:: Multi-step reaction with 6 steps

1: 5 percent KOH / 0 °C

2: acetic acid / 1 h / 80 °C

3: 60 percent / Et₃N / CH₂Cl₂ / 0.25 h / 0 °C

4: 75 percent / 1 M KOtBu / tetrahydrofuran; 2-methyl-propan-2-ol / 0.5 h / 60 °C

5: 4 percent / MeONa / methanol / Ambient temperature

6: Heating

With potassium hydroxide; potassium tert-butylate; sodium methylate; triethylamine; In tetrahydrofuran; methanol; dichloromethane; acetic acid; tert-butyl alcohol;

Reference yield:

: 69945-45-5,80582-73-6,129785-51-9,139012-51-4,140696-30-6
(+/-)-(3/4,5,6)-4-bromo-5,6-epoxy-3-hydroxycyclohexene

: 87160-99-4
N-((1S,2R,3S,6R)-3-Methoxy-7-oxa-bicyclo[4.1.0]hept-4-en-2-yl)-4-methyl-benzenesulfonamide

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / ZnSO₄ / methanol / 1 h / Heating

2: 95 percent / 1M tBuOK / tetrahydrofuran; 2-methyl-propan-2-ol / 0.5 h / 0 °C / further reagent: 5percent KOH/MeOH

3: 6 percent / Et₃N, (MeSO₂)2O / CH₂Cl₂ / 120 h / 0 °C

4: Heating

With potassium tert-butylate; triethylamine; zinc(II) sulfate; Methanesulfonic anhydride; In tetrahydrofuran; methanol; dichloromethane; tert-butyl alcohol;