1-phenylazagermatrane

Base Information

Chemical Name:1-phenylazagermatrane
CAS No.:499158-48-4
Molecular Formula:C₁₂H₂₀GeN₄
Molecular Weight:292.908
Hs Code.:

Synonyms:

Suppliers and Price of 1-phenylazagermatrane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-phenylazagermatrane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-phenylazagermatrane

There total 1 articles about 1-phenylazagermatrane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 4097-89-6
2,2',2''-triaminotriethylamine

: 53445-75-3
phenyltris(dimethylamino)germane

: 499158-48-4
1-phenylazagermatrane

Guidance literature:: In neat (no solvent); byproducts: dimethylamine; under Ar; mixt. of Ge compd. and tetraamine (molar ratio 1:1) stirred at130-135°C for 2 h; cooled to room temp.; recrystd. from hot n-heptane; elem. anal.;
DOI:10.1021/om020708h

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 499158-48-4
1-phenylazagermatrane

: 500127-28-6
1-phenyl-N,N',N''-tris(trimethylsilyl)azagermatrane

Guidance literature:: With n-butyl lithium; In tetrahydrofuran; hexane; under Ar; n-BuLi in hexane added dropwise at -78°C to stirred soln. of Ge compd. in THF; stirred (-78°C, 10 min and room temp., 4 h); soln. of Me3SiCl in THF added dropwise at -40°C with stirring; stirred (room temp., 12 h); volatiles removed under reduced pressure; n-hexane added; filtered; volatiles removed from filtrate in vac.; detd. by (1)H NMR spectra; yellow oil contained minor amt. of title compd.;
DOI:10.1021/om020708h