{trans-(PPh₃)2Pt(CN(C₆H₄-p-OMe))Cl}BF₄

Base Information

Chemical Name:{trans-(PPh₃)2Pt(CN(C₆H₄-p-OMe))Cl}BF₄
CAS No.:110313-73-0
Molecular Formula:BF₄*C₄₄H₃₇ClNOP₂Pt
Molecular Weight:975.069
Hs Code.:

{trans-(PPh<sub>3</sub>)2Pt(CN(C<sub>6</sub>H<sub>4</sub>-p-OMe))Cl}BF<sub>4</sub>

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Chemical Property of {trans-(PPh₃)2Pt(CN(C₆H₄-p-OMe))Cl}BF₄

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Technology Process of {trans-(PPh₃)2Pt(CN(C₆H₄-p-OMe))Cl}BF₄

There total 1 articles about {trans-(PPh₃)2Pt(CN(C₆H₄-p-OMe))Cl}BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 14104-20-2
silver tetrafluoroborate

: 10199-34-5,14056-88-3,15604-36-1
cis-dichlorobis(triphenylphosphine)platinum(II)

: 10349-38-9
p-methoxyphenylisonitrile

: 110313-73-0
{trans-(PPh₃)2Pt(CN(C₆H₄-p-OMe))Cl}BF₄

: silver(I) chloride

Guidance literature:: In dichloromethane; acetone; under inert gas; suspn. of Pt complex in CH2Cl2 treated with AgBF4 in acetone for 1 h at room temp.; pptd. AgCl removed; addn. ofp-MeOC6H4NC in CH2Cl2 at 0°C; reaction mixt. allowed to reach room temp.; soln. concd. under reduced pressure, addn. of Et2O; ppt. filtered off, recrystd. from CH2Cl2/Et2O; elem. anal.;

Reference yield: 85.0%

: 13755-29-8
sodium tetrafluoroborate

: 109-72-8,29786-93-4
n-butyllithium

: 110313-73-0
{trans-(PPh₃)2Pt(CN(C₆H₄-p-OMe))Cl}BF₄

: 2576-47-8
2-bromoethylamine hydrobromide

: 111139-87-8
trans-{(PPh₃)2Pt(CN(C₆H₄-p-OMe)CH₂CH₂N(H))Br}BF₄

Guidance literature:: In tetrahydrofuran; hexane; under inert gas; addn. of the ammonium salt suspended in THF to n-BuLi at 0°C; addn. of the Pt complex; reaction mixt. allowed to reach room temp.; stirring for 45 min; evapn.; residue dissolved in acetone, soln. treated with NaBF4; stirring (3h); reaction mixt. taken to dryness, residue dissolved in CH2Cl2; filtration, addn. of n-pentane yields the solid product; elem. anal.;

Reference yield: 63.0%

: 503-29-7
azetidine

: 110313-73-0
{trans-(PPh₃)2Pt(CN(C₆H₄-p-OMe))Cl}BF₄

: trans-BF₄{monochloro(triphenylphosphine)2(C(NCH₂CH₂CH₂)para-methoxyanilino)}platinum(II)

Guidance literature:: In tetrahydrofuran; To suspn. of Pt compd. is added azetidine, then react. mixture is stirred at 0°C, is allowed to warm to room temp., mixture is stirred at room temp. for 10 h (under N2).; monitored by IR, elem. anal.;